@Research Paper
<#LINE#>Viscosities and densities for binary mixtures of 1, 2-ethanediol and water at higher temperature<#LINE#>G.P. @Borse <#LINE#>1-7<#LINE#>1.ISCA-RJCS-2015-103.pdf<#LINE#>Department of Chemistry, R.L. College, Parola–425 111, MS, India<#LINE#>18/7/2015<#LINE#>16/1/2017<#LINE#>Viscosities and densities of the binary mixtures of 1,2-ethanediol with water were measured at 318.15, 320.15, 322.15, 324.15, 326.15 and 328.15 K. This experimental data were used to calculate excess molar volume (VE), viscosity deviations (&#61508;n) and excess Gibbs free energy of activation &#61508;GE* of viscous flow. These results have been discussed in terms of molecular interaction at different temperatures.  The excess molar volume (VE) and viscosity deviation (&#61508;n) values were found to be negatives at all temperatures.  The molecular interactions existing between the components were also discussed.<#LINE#>Dean J.A. (1999).@Lange’s Handbook of Chemistry.@13th Edition, McGraw-Hill, New York, Chapter 1 and 7, 186 and 600.@Yes$Pal A. and Sharma S. (1998).@Excess molar volumes and viscosities of 1-propanol + Ethylene glycol Monomethyl + Ethylene glycol Dimethyl, + Dimethylene glycol + Diethylene glycol Diethyl, and + Diethylene Glycol Dibutyl Ethers at 298.15 K.@Journal of Chemical and Engineering Data, 43, 532-536.@No$Dean J.A. (1990).@Lange’s Handbook of Chemistry.@McGraw-Hill, 13th Edition, (Chapter 7), 600.@Yes$Stefano OIttani., Daniele Vitalini., Fabio Cometti. and Carlo C. (2002).@Densities, Viscosities and refractive indices of poly (ethylene glycol) 200 and 400 + Cyclic Ethers at 303.15 K.@J. of Chemical and Engineering Data, 47, 1197-1204.@Yes$Nikam P.S., Shirsat L.N. and Hasan M. (1998).@Density and viscosity studies of binary mixtures of acetonitrile with methanol, ethanol, propan-1-ol, propan-2-ol, butan-1-ol, 2-methylpropan-1-ol and 2-methyl propan-2-ol at (298.15, 303.15, 308.15 and 313.15) K.@J. of Chemical and Engineering Data, 43, 732-737.@Yes$Palepu R. and Macneil J.G. (2001).@Viscosities and Densities of Binary Mixtures of 2,2,2-Trichloethanol with substituted Anilines.@Aus. J. of Chemistry, 41, 791-797.@Yes$Oswal S.L., Prajapati K.D., Oswal P., Ghael N.Y. and Ejardar S.P. (2005).@Viscosity of Binary Mixtures of 1-alkanol + Cyclohexane, 2-alkanol + Cyclohexane and 1-alkanol + Methylcyclohexane at 303.15 K.@J of Molecular Liquids, 116, 73-82.@Yes$Pal A. and Kumar H. (2001).@Excess Molar Volumes and Viscosities of Binary Liquid Mixtures containing Polyethes and pyrrolidine-2-one at 298.15 K.@Indian Journal of Chemistry, 40A, 598-604.@No$Lurdes S., Alver Silva J. and Fatima F. (1990).@Densities and Viscosities of Binary and Ternary Liquid Systems containing Xylenes.@J. Chem Eng. Data, 35, 288-291.@Yes$Bawa M.J., Lomte S.B., Lande M.K. and Arbad B.R. (2009).@Thermodynamic properties of Binary Liquids Mixtures containing 1,2-ethanediol and primary alcohols at different temperatures.@J. Indian Chem. Soc., 86, 1190-1196.@Yes$Pal A. and Gaba Rekha (2007).@Volumetric, acoustic, Viscometric and spectroscopic properties for binary mixtures of dipropylene glycol dimethyl ether + n-alkalyamine mixtures at 298.15 K.@J. Indian Chem. Soc., 84, 661-673.@Yes$Kapdi U.R., Hundiwale D.G., Patil N.B., Lande M.K. and Patil P.R. (2001).@Studies of Viscosity and excess molar volume of binary mixtures of propan-1, 2-diol with water at various temperatures.@Fluid Phase Equilibria, 192, 63-70.@Yes$Shu-da Chem., Quen-Fang Lei. and Wen-Junfang (2005).@Viscosities and densities for binary mixtures of N-methylpiperazine with methanol, ethanol, n-propanol, iso-propanol, n-butanol and isobutanol at 293.15, 298.15 and 303.15 K.@fluid phase Equilibria, 234, 1-2, 22-33.@No$Abminabhavi T.M. and Kamalika B. (1998).@Density, Viscosity, refractive Index and Speed of Sound in Binary Mixtures of Methyl acetate + Ethylene Glycol or + Poly (ethylene glycol) in the Temperature Interval (298.15 – 308.15 K).@J. Chem and Engg Data, 43, 852-855.@No
<#LINE#>Synthesis, spectral, thermal and biological studies of some unsymmetrical Schiff base metal complexes<#LINE#>G.B. @Pethe,A.D. @Bansod,J.B. @Devhade,A.K. @Maldhure,A.S. @Aswar <#LINE#>8-12<#LINE#>2.ISCA-RJCS-2016-064.pdf<#LINE#>Department of Chemistry, Sant Gadge Baba Amravati University Amravati-444 602, MS, India@Department of Chemistry, Sant Gadge Baba Amravati University Amravati-444 602, MS, India@Department of Chemistry, Sant Gadge Baba Amravati University Amravati-444 602, MS, India@Department of Chemistry, Sant Gadge Baba Amravati University Amravati-444 602, MS, India@Department of Chemistry, Sant Gadge Baba Amravati University Amravati-444 602, MS, India<#LINE#>22/3/2016<#LINE#>14/12/2016<#LINE#>Unsymmetrical tetradentate Schiff base derived from Salicylaldehyde, 2-hydroxy-3-methoxy benzaldehyde and ethylenediamine and its complexes with VO(IV), Cr(III), Mn(III), Fe(III) and UO2(VI)  have been prepared. These complexes have been characterized by elemental analysis, IR and electronic spectra, magnetic moments, XRD and thermal analysis. The complexes are colored and stable in air at room temperature. The thermal behavior of  metal complexes shows that  the hydrated complexes loses water molecules of hydration in the first step; followed by decomposition of ligand molecule in the subsequent steps leaving behind metal oxide as end product. The IR spectra suggest that ligand behaves as bi-negative tetradentate nature with ONNO donor sequence sites of the azomethine nitrogen and phenolic oxygen towards central metal ion. The solid state electrical conductivity of compounds was measured by two probe method over 313-403 K temperature range. Solid state electrical conductivity studies reflect semiconducting behavior of the compounds in the studied temperature range as their conductivity increases with increase in temperature. The powder XRD analysis of VO (IV) complex suggests the triclinic crystal system. The ligand and its complexes were screened for their biological activity against bacteria E. coli , S. abony, S. aureus and B. subtilis by the agar well diffusion method and most of complexes  were found to be moderately active against the organisms.<#LINE#>Priyarega S., Prabhakaran R., Aranganayagam K.R, Karvembu R. and Natarajan K. (2007).@Synthetic and catalytic investigations of ruthenium (III) complexes with triphenylphosphine/triphenylarsine and tridentate Schiff base.@Appl. Organomet. Chem., 21, 788-793.@Yes$Shibuya Y., Nabari K., Kondo M., Yasue S., Maeeda K., Uchida F. and Kawaguchi H. (2008).@The Copper(II) Complex with Two Didentate Schiff Base Ligands. The Unique Rearrangment that Proceeds under Alcohol Vapor in the Solid State to Construct Noninclusion Structure.@Chem. Lette, 37, 78-79.@Yes$Maurya M.R., Bharti N., Naqvi F. and Azam A. (2002).@Synthesis and antiamoebic activity of new cyclooctadiene ruthenium (II) complexes with 2-acetylpyridine and benzimidazole derivatives.@Bio-Inorg. Med. Chem. Lett., 10, 2243-45.@Yes$Li J., Xu B., Jiang W., Zhou B., Zeng W. and Qin S. (2008).@Catalytic epoxidation performance and dioxygen affinities of unsymmetrical Schiff base transition–metal complexes with pendant aza-crown or morpholino groups.@Trans. Met. Chem., 33, 975-979.@Yes$Minnersand J.O. and Sinn E. (1973).@Alkoxy and Phenoxy Bridged Dimeric Copper(II) Complexes with Salicylaldimine Ligands.@Bull. Chem. Soc. Jpn, 46, 1457-1461.@Yes$Cros G. and Laurent J.P. (1988).@Unusual dinuclear copper(II) and nickel(II) complexes of a novel Schiff base deriving from 2-aminoethanol.@Inorg. Chim. Acta,142, 113-117.@Yes$Costes J.P., Dahan F. and Laurent J.P. (1984).@Experimental proof of the existence of the “half-unit” 7-amino-4-methyl-5-aza-3-heptene-2-one (aeh). Crystal structure of a novel dibromo-bridged dicopper(ii) complex (cuaebr)2.@J. Coord, Chem., 13, 355-362.@Yes$Golchoubian H. , Nazari O. and Kariuki B. (2010).@A new copper(II) complex of unsymmetrical tetradentate ligand generated in situ: synthesis and molecular structure.@Inorganica Chimica Acta.@Yes$Jebbar-Sid S.D., Benali-Baitich O. and Deloume J.D. (1997).@Synthesis, characterization and electrochemical behaviour of some copper(II) complexes with linear and tripodal tetradentate ligands derived from Schiff bases.@Polyhedron, 16, 2175-2182.@Yes$Christensen O.T. (1901).@Studies of Manganese compounds, Manganese acetate (II) and alums of manganese.@Z.Anorg. Allg. Chem., 27, 321-340.@No$Singh D.P., Kumar K. and Sharma C. (2009).@Antimicrobial active macrocyclic complexes of Cr(III), Mn(III) and Fe(III) with their spectroscopic approach.@Eur. J. Med. Chem., 44, 3299-3304.@Yes$Yaul A.R., Dhande V.V., Suryawanshi N.J. and Aswar A.S. (2009).@Synthesis, Structural Investigation and Biological Studies of Some Transition Metal Chelates of Acid Hydrazone.@Polish J. Chem,83, 565-572.@Yes$Maurya M.R., Khurana S., Schulzke C. and Rehder D. (2001).@Dioxo- and Oxovanadium(V) Complexes of Biomimetic Hydrazone ONO Donor Ligands: Synthesis, Characterisation, and Reactivity.@Eur. J. Inorg. Chem., 3, 779-788.@Yes$Nakamota (1970).@Infrared Spectra of Inorganic and Coordination Compounds.@New York, Willey.@Yes$Hay R.W. and Hassan M.M. (1997).@Copper(II), nickel(II) and zinc(II) complexes of N,N&#8242;,N&#8243;,N&#8243;@Polyhedron, 16, 2205-2216.@Yes$Adam D.M. (1967).@Metal Ligand and Related Vibrations.@London, Arnold.@Yes$Nag J.K., Pal S. and Sinha C. (2005).@Synthesis and characterization of cobalt(II), nickel(II), copper(II), palladium(II) and dioxouranium(VI) complexes of the antipyrine Schiff base of 3-formylsalicylic acid.@Trans. Met. Chem., 30, 523-526.@Yes$Maurya R.C., Mishra D.D. and Pillai V. (1995).@Studies on Some Novel Mixed-Ligand Oxovanadium (IV) Complexes Involving Acetylacetone and Nitrogen or Oxygen Donor Organic Compounds.@Synth. React. Inorg. Met. Org. Chem., 25, 1127-1141.@Yes$Dubey R.K., Dubey U.K. and Mishra C.M. (2008).@Synthesis and physicochemical characterization of some Schiff base complexes of chromium (III).@Indian J. Chem., 47A, 1208-1212.@Yes$Howlader M.B.H, Islam M.S. and Karim M.R. (2000).@Synthesis of some 16-membered macrocyclic complexes of chrornium(III), manganese(II), iron(III), cobalt(II), nickel(II) and copper(II) containing a tetraoxooctaazacyclohexadecane ligand.@Indian J. Chem., 39A, 407-409.@Yes$Hui W., Zcnglu L., Yulan Z. and Shaozu W. (1995).@New Metal Complexes Derived From 1-Ferrocenecarbonyl-4-Phenyl-3-Thiosemicarbazide with some Transition Metal Ions.@Synth. React. Inorg. Met. Org. Chem., 25, 1143-1153.@Yes$Mishra A.P. and Pandey L.R. (2005).@Synthesis, characterization and solid state structural studies of oxovanadium (IV) – O, N donor Schiff base chelates.@Indian J. Chem., 44A, 94-97.@Yes$Katon J.E. (1968).@Organic Semiconducting Polymers.@New York, Marcel Dekker(Ed).@Yes$Koca M., Dagdelen F. and Aydogdy Y. (2004).@Thermal and optical properties of benzofuran-2-yl 3-phenyl-3-methylcyclobutyl thiosemicarbazone.@Matter. Lett., 58, 2901-2905.@Yes$Berrington A. and Gould F.K. (2001).@Use of antibiotic locks to treat colonized central venous catheters.@J. Antimicrob. Chemother, 48 (5), 597-603.@Yes$Singh D.P., Kumar R. and Singh J. (2009).@Synthesis and spectroscopic studies of biologically active compounds derived from oxalyldihydrazide and benzil, and their Cr(III), Fe(III) and Mn(III) complexes.@Eur. J. Med. Chem., 44, 1731-1736.@Yes
<#LINE#>Synthesis and characterization of carboxyl-functionalized benzimidazolium based ionic liquids as efficient and recyclable catalysts<#LINE#>Prashant Narayan @Muskawar,Pundlik Rambhau @Bhagat <#LINE#>13-24<#LINE#>3.ISCA-RJCS-2016-100.pdf<#LINE#>Department of Chemistry, Amolakchand Mahavidyalaya, Yavatmal, 445 001, India@Organic Chemistry Division, SAS, VIT University, Vellore, 632 014, India<#LINE#>22/3/2016<#LINE#>18/12/2016<#LINE#>A series of Task specific novel COOH-functionalized benzimidazolium-based ionic liquids (CFBILs), N-alkyl-N&#8242;-carboxyethyl benzimidazolium bromide ([N-Cn, N&#8242;-CH2CH2CO2H-Bim] Br, n=2,3,4,6,8), was successfully synthesized and characterized by FT-IR, NMR and HR-MS. All these Task-specific benzimidazolium based ionic liquids was synthesized by simple neutralization process at moderate condition possessing Bronsted acid site i.e. COOH. A series of benzimidazolium based ionic liquids with varying alkyl chain on nitrogen terminal showing the different thermal stability. When the alkyl chain on the benzimidazolium cation were longer like octyl, decomposing temperature and solubility in aqueous solvent goes on decreasing compare to lower alkyl chains like ethyl, propyl, butyl, hexyl. From the literature it reveal that all the these Carboxyl functionalized ionic liquids can be useful for variety of applications like organic transformation, tribological performance, photocatalytic application, solubilizing and extraction of  lanthanide and actinides metals, electrochemistry for sensing ATP and enzyme immobilization, selective separation of proteins, micelle formation etc.<#LINE#>Xue H., Verma R. and Shreeve J.M. (2006).@Review of ionic liquids with fluorine containing anions.@J. Fluorine Chem., 127, 159–176; (b) Wasserscheid, P., & Welton, T. (2002). Ionic Liquid in Synthesis. Wiley-VCH & CoKGaA: Germany.@Yes$Buzzeo M.C., Hardacre C. and Compton R.G. (2004).@Use of room temperature ionic liquids in gas sensor design.@Anal. Chem., 76, 4583–4588.@Yes$Muskawar P.N., Kumar S.S. Bhagat P.R. (2013).@Carboxyl-functionalized ionic liquids based on Benzimidazolium cation: Study of Hammett values and catalytic activity towards one-pot synthesis of 1-amidoalkyl naphthols.@J. Mol. Catal. A: Chem., 380, 112–117.@Yes$Davis Jr. J.H. (2004).@Task-Specific Ionic Liquids.@Chem. Lett., 33, 1072.@Yes$Miao W. and Chan T.H. (2003).@Exploration of ionic liquids as soluble supports for organic synthesis demonstration with a Suzuki coupling reaction.@Org. Lett., 5, 5003.@Yes$Bates E.D., Mayton R.D., Ntai I. and Davis J.H. (2002).@CO2 capture by a task-specific ionic liquid.@J. Am. Chem. Soc., 124, 926-929.@Yes$Li D.M., Shi F., Peng J.J., Guo S. and Deng Y.Q. (2004).@Application of functional ionic liquids possessing two adjacent acid sites for acetalization of aldehydes.@J. Org. Chem., 69, 3582-3584.@Yes$Davis Jr. J.H., Forrester K.J.T. and Merrigan J. (1998).@Novel organic ionic liquids (OILs) incorporating cations derived from the antifungal drug miconazole.@Tetrahedron Lett., 49, 8955-8958.@Yes$Karthikeyan P., Muskawar P.N., Bhagat P.R. and Senthil Kumar S. (2012).@A novel CuCl2/BIL catalyst for direct oxidation of alcohol to acid at ambient temperature.@Cat. Commun., 26, 189–193.@Yes$Karthikeyan P., Aswar S.A., Muskawar P.N., Bhagat P.R. and Sythana S.K. (2012).@Development of an efficient solvent free one-pot Heck reaction catalyzed by novel palladium (II) complex-via green approach.@J. Mol. Cat. A: Chem., 358, 112–120.@Yes$Karthikeyan P., Aswar S.A., Muskawar P.N., Bhagat P.R., Senthil Kumar S. and Sythana S.K. (2012).@Selective oxidation of alcohol to carbonyl compound catalyzed by l-aspartic acid coupled imidazolium based ionic liquid.@J. Mol. Liq. 173, 180–183.@Yes$Wang X., Li Yu, Jiao J., Zhang H., Wang R. and Chen H. (2012).@Aggregation behavior of COOH-functionalized imidazolium-based surface active ionic liquids in aqueous solution.@J. Mol. Liq., 173, 103–107.@Yes
<#LINE#>Synthesis, compositional and spectral studies of some transition metal complexes with 3-aminolawsonoxime<#LINE#>A.M. @Nemade,K.D. @Patil,V.C. @Kolhe <#LINE#>25-31<#LINE#>4.ISCA-RJCS-2016-216.pdf<#LINE#>Department of Chemistry, Dr. A.G.D. Bendale Mahila Mahavidyalaya, Jalgaon-425001, MS, India@Department of Chemistry, Bhusawal Arts, Science and P O N Commerce College, Bhusawal-425201, MS, India@Ex. Director, BCUD, North Maharashtra University, Jalgaon-425001, MS, India<#LINE#>24/8/2016<#LINE#>2/12/2016<#LINE#>The metal complexes which were synthesized from organic compounds containing oxygen and nitrogen donors are of great interest for structural study. The derivative of quinine, lawson (2-hydroxy-1,4- naphthoquinone) is natural coloring matter and is also indicated in the treatment of various ailment and diseases and as disinfectant. The hydroxyl derivative of 1,4- naphthoquinone is of great interest due to its slight therapeutic property. The general method is adopted for preparation of oxime, the ligand 3-Aminolawsoneoxime (3-Amino-2-hydroxy, 4-keto 1-naphthoxime) was synthesized from 3-Amino-2-hydroxy-1, 4-Naphthoquinone. Some of the transition metal such as Fe, Co, Ni and Cu are in form of their salts were used for the complexation. The synthesized complexes were characterized by various physico-chemical techniques such as compositional studies and spectral studies. It has been found that the probable formulation of the complexes is M L (H2O) 2. Wherein M : L stoichiometry  is 1:1.The spectral data  while and magnetic studies of the metal complexes proposed  distorted tetrahedral structure for Fe, Co and Ni complexes and  square planer structure may be proposed for copper complex.<#LINE#>Schnitzer M. and Khan S.U. (1972).@Humic Substances in the Environment.@Marcel Dekker: New York P-17.@Yes$Morton B.A. (1965).@Biochemistry of Quinone.@Academic Press New York , 169.@No$R.E. O’lson Ed (1972).@Perspective in Biological Chemistry.@Marcel Dekker, Inc. New York, 119.@No$Gupta A. D., (1948).@Charak Samita composed by Maharshi Agnivesh (trans.).@Second Edition, Bhargav Pustkalaya, Varanasi, 503.@No$Padhye S.B., Amodikar S.A., Vakil J.R. and Pendse G.S. (1974).@14th Annual conference of Association of Microbiologist of India.@1, 34.@No$Shashri S.P. (2009).@Sushrut Samhita.@Swaraswti Pustakalaya, Kanpur, India, 359.@No$Kelkar V.D. (1979).@Metal Chelates of Some Halogen hydroxy-naphthoquinone.@Doctorate Thesis, University of Poona.@No$Padhye M.V. (1980).@Study on Metal Chelates of some o-hydroxy quinone derivatives.@Doctorate Thesis, University of Poona.@No$Jagtap S.B., Chikate R.C., Kulkarni B.A., Yemul O. and Ghadage R. (2004).@T hermal, spectral and magnetic properties of 2-hydroxy-1,4-naphthoquinone monoximates of Ho(III), Er(III) and Yb(III).@Journal of Thermal Analysis and Calorimetry, 78(1), 251-262@Yes$Garge P.L., Padhye S.B. and Gupta M.P. (1988).@High-spin iron(II) complexes of ortho functionalized para-quinones as models for quinone binding sites in reaction centers of  photosynthetic bacteria.@Inorg. Chim.Acta. 152(1), 37-40.@Yes$Garge P., Chikate R., Padhye S. and Tuchagues J.P. (1989).@Iron(II) complexes of o-functionalised para naphtho- quinones. 1. Syn-thesis, characterization, electronic structure and magnetic properties.@Inorg. Chim Acta., 157(2), 239-249.@Yes$Garge P., Chikate R., Padhye S. and Tuchagues J.P.  (1990).@Iron (II) complexes of o-functionalised p- naphtho-quinones.2 crystal and molecular structure of bis(aquo) bis (lawsone) iron(II) and intermolecular magnetic exchange interactions in bis (3-aminolawsone iron(II).@Inorg. Chem., 29, 3315.@Yes$Kolhe V.C. (1983).@Studies on Transition Metal Complexes of some Biological Electron Transfer Reactions.@Doctorate Thesis, University of Poona.@No$Bajaj H.A. (1992).@Synthesis and characterization of lanthanide complexes with 3-amino, 2-hydroxy 1, 4- naphthoquinone.@M.Phil. Thesis, University of Poona.@No$Patil K.D., Thombare A.L. and Rupali Patil (2014).@Synthesis, Characterization, Thermogravimetric Studies of Bis-Phthiocolmonoximato Iron III Adducts.@Int. Journal. Chem. Sci., 12(4), 1169-1178.@No$Pierpont C.G. and Buchanan R. M. (1981).@Transition metal complexes of o-benzoquinone, o-semiquinone and catecholate ligands.@Coord. Chem. Rev., 38, 45.@Yes$Magers K.D., Smith C.G. and Sawyer D.T. (1978).@Polarographic and spectroscopic studies of the manganese(II), (III) and (IV) complexes formed by polyhydroxy ligands.@Inorg. Chem, 17, 715.@Yes$Nagase Y. and Matsumoto U. (1961).@Studies on Application of Naphthoquinone Derivatives as Organic Reagents. II. Precipitation and Color Reactions of 3-Aminolawsone with Metal Ions.@Yakugaku Zansshi, 81, 627.@No$Nemade A.M. and Kolhe V.C. (2016).@The Study of Thermal and Magnetic properties of Fe (II), Co(II), Ni(II) and Cu(II) Metal Complexes with 3 Aminolawsone oxime.@Journal of Chemical and Pharmaceutical Research, 8(4), 878.@No$Patil K.D. (1992).@Ligand Induced Reactivity Pathway in Nickel Oximates of Vitamin K Analogues.@M Phil. Thesis, University of Poona.@No$Vinogradov S.N. and Linnel R.H. (1986).@Hydrogen Bonding.@Van Nostrand Reinhold Company, New York.@No$Gaultier J. and Hauw C. (1965).@Structures crystalline des derives et 2,3 dela  naphthoquinone 1,4 III, chloro -2- amino naphthoquinone.@Acta. Cryst., 19, 585.@No$Padhye S.B. (1973).@Studies in Some Naturally Occurring Isomeric Juglones.@Doctorate Thesis, University of Poona.@No$Rane S.Y. (1978).@Metal Chelates of Methylated Juglones.@Doctorate Thesis, University of Poona.@No$Kelkar V.D. (1979).@Metal Chelates of some Halogen hydroxy naphthoquinone.@Doctorate Thesis, University of Poona.@No$Chakaravorty A. (1974).@Structural chemistry of transition metal complexes of oxime.@Co-ord.Chem.Rev., 13, 1.@Yes$Kumar D.H. (1988).@Study the complexes of metal oximates.@M. Phil Thesis, University of Poona.@No$Rane S.Y., Padhye S.B., Natu G. N., Kumbhar A.S. and Khan E. M. (1989).@Kinetics of dehydration in chelates of quinones involved in Photosystem II.@Journal of Thermal Analysis, 35, 2321@Yes$Condrate R.A. and Nakamto K. (1965).@Infrared Spectra and Normal Coordinate Analysis of Metal Glycino Complexes.@J. Chem. Phys., 42, 2590.@Yes$Dwivedi B.K., Bhatnagar K. and Shrivastav A.K. (1986).@Coordination Compounds of Tin(II) Chloride, Bromide and Isothiocyanate with Schiff Bases Derived from 2-Hydroxy-1-naphthaldehyde.@Synth. React. Inorg. Met. Org. Chem., 16, 715.@Yes
<#LINE#>Comparative assessment of heavy metals in soil, weed species and waste water after used for irrigation in industrial zones of Ichalkaranji city<#LINE#>Pravin B. @Kamble,Dhairyasheel B. @Patil,S.B. @Bhamburdekar <#LINE#>32-36<#LINE#>5.ISCA-RJCS-2016-240.pdf<#LINE#>P.G. Department of Botany, Plant Physiology Section, Krishna Mahavidyalaya, Rethare Bk., Tal-Karad, Dist –Satara, MS, India@P.G. Department of Botany, Plant Physiology Section, Krishna Mahavidyalaya, Rethare Bk., Tal-Karad, Dist –Satara, MS, India@P.G. Department of Botany, Plant Physiology Section, Krishna Mahavidyalaya, Rethare Bk., Tal-Karad, Dist –Satara, MS, India<#LINE#>3/12/2016<#LINE#>28/12/2016<#LINE#>The toxic heavy metal concentrations in soil, weed species and waste water used for irrigation in industrial zones of Ichalkaranji were investigated. The industrial zone polluted soils showed higher levels of toxic heavy metal soil contamination as compared to non-industrial zones agricultural soils. The toxic heavy metal concentration in soils is above the maximum permissible levels for Hg (Mercury), Cd (Cadmium) and As (Arsenic) respectively. The heavy metal content of effluent, Panchaganga River and groundwater in industrial zones of Ichalkaranji were also investigated. The distribution of heavy metals reported similar patterns in weed species in the industrial zones of Ichalkaranji.<#LINE#>Vigneswaran S. and Sundaravadivel M. (2004).@Recycle and reuse of domestic waste water.@waste water, reuse and reclamation.Unesco Eolss,@No$Jeevan Rao K. and Shantaram M.V. (1999).@Potentially toxic elements in soils treated with urban solid wastes.@Indian J of Environ. Health, 41(4), 364-368.@Yes$Nair K.M. (1999).@Heavy metal pollution of soils of a watershed contaminated by sewage and industrial effluent from Bangalore urban area.@National Bureau of soil studies, Bangalore. Ph.D. thesis.@Yes$Kaiser K. and Guggenberger G. (2003).@Mineral surfaces and soil organic matter.@European Journal of Soil Science, 54(2), 219-236.@Yes$Marsh A.S. and Siccama T.G. (1997).@Use of formerly plowed land in New England to monitor the vertical distribution of lead , zinc and copper  in mineral soil.@Water Air Soil Pollution, 95(1), 75-85.@Yes$WHO (2011).@Guidelines for drinking water quality.@, 4th edn. World Health Organization, Geneva.@Yes$Adhikari T., Ajaykumar K., Singh V. and Subba Rao A. (2010).@Phytoaccumulation of lead by selected wetland plant species.@Communication in soil science and plant analysis, 41(22), 2623-2632.@Yes$Raskin I. and Ensley B.D. (2000).@Phytoremediation of Toxic Metals: Using Plants to Clean Up the Environment.@John Wiley & Sons, Inc., New York.@Yes$Arao T. and AE N. (2003).@Genotypic variations in cadmium levels of rice grain.@Soil science. Plant Nutr., 49(4), 473-479.@Yes$Murakami M., AE N. and Ishikawa S. (2007).@Phytoextraction of cadmium by rice (Oryza sativa L.), soybean (Glycine max (L.) Merr.) and maize (Zea mays L.).@Environ. Pollut., 145(1), 96-103.@Yes$Ghosh M. and Singh S.P. (2005).@A comparative study of cadmium phytoextraction by accumulator and weed species.@Environment pollution, 133(2), 365-371.@Yes$Mellem J.J., Baijnath H. and Odhav B. (2012).@Bioaccumulation of Cr, Hg, As, Pb, Cu and Ni with the ability for hyperaccumulation by Amaranthus dubius.@African journal of Agricultural research. 7(4), 591-596.@Yes
<#LINE#>Dimethyl aminomethylene ketones and &#945;, &#946;-unsaturated ketones with thiazolyl substituted 4-thiazolidinone framework: versatile reactive intermediates to synthesize a variety of medicinally potent heterocycles<#LINE#>Nidhi @Jain,Radha @Chaudhary,Bhawani @Singh <#LINE#>37-44<#LINE#>6.ISCA-RJCS-2016-241.pdf<#LINE#>Department of Chemistry, Banasthali Vidyapith, Banasthali, Rajasthan, India@Department of Chemistry, Geetanjali Institute of Technical Studies, Dabok, Udaipur, Rajasthan, India@Department of Pure and Applied Chemistry, University of Kota, Kota, Rajasthan, India<#LINE#>11/12/2016<#LINE#>28/12/2016<#LINE#>The reactive intermediates i.e. dimethyl aminomethylene ketones (NJ-2016-004) and &#945;,&#946;-unsaturated ketones (NJ-2016-005a-d) possessing thiazolyl substituted 4-thiazolidinone framework have been synthesized from the reaction of thiazolyl substituted 4-thiazolidinones with N,N-dimethylformamide dimethylacetal (DMF DMA) and substituted benzaldehydes respectively. Schematic reaction schemes are presented as Reaction Scheme: NJ-01 and Reaction Scheme: NJ-02. Formation of the compounds was ensured on the basis of analytical IR, NMR and MS spectral data.<#LINE#>Tanaka A., Sakai H., Motoyama Y., Ishikawa T. and Takasugi H. (1994).@Antiplatelet agents based on cyclooxygenase inhibition without ulcerogenesis. Evaluation and synthesis of 4,5-bis(4-methoxyphenyl)-2-substituted-thiazoles.@J. Med. Chem., 37(8), 1189-1199.@Yes$Richard F., Clark R.F., Zhang T., Wang X., Wang R., Zhang X., Camp H.S., Beutel B.A., Sham H.L. and Gu Y.G. (2007).@Phenoxy thiazole derivatives as potent and selective acetyl-CoA carboxylase 2 inhibitors: Modulation of isozyme selectivity by incorporation of phenyl ring substituents.@Bioorg. Med. Chem. Lett., 17(7), 1961-1965.@Yes$Barradas J.S., Errea M.I., D@Imidazo[2,1-b]thiazole carbohydrate derivatives: Synthesis and antiviral activity against Junin virus, agent of Argentine hemorrhagic fever.@Eur. J. Med. Chem., 46(1), 259-264.@Yes$Helal M.H.M., Salem M.A., El-Gaby M.S.A. and Aljahdali M. (2013).@Synthesis and biological evaluation of some novel thiazole compounds as potential anti-inflammatory agents.@Eur. J. Med. Chem., 65(1), 517-526.@Yes$Omer A.M.E. and Eshba N.H. (1984).@Synthesis and biological evaluation of new 2,3-dihydrothiazole derivatives for antimicrobial, antihypertensive, and anticonvulsant activities.@J. Pharm. Sci., 73(8), 1166-1168.@Yes$Sattigeri V.J., Soni A., Singhal S., Khan S., Pandya M., Bhateja P., Mathur T., Rattan A., Khanna J.M. and Mehta A. (2005).@Synthesis and antimicrobial activity of novel thiazolidinones.@ARKIVOC, 2, 46-59.@Yes$Mistry B.M. and Jauhary S. (2013).@Synthesis and in vitro antimicrobial and anti-tubercular evaluation of some quinoline-based azitidinone and thiazolidinone analogues.@Med. Chem. Res., 22(2), 635-646.@Yes$Ottana R., Maccari R., Barreca M.L., Bruno G., Rotondo A., Rossi A., Chiricostr G., Di Paola R., Sautebin L., Cuzzocrea S. and Vigorita M.G. (2005).@5-Arylidene-2-imino-4-thiazolidinones: Design and synthesis of novel anti-inflammatory agents.@Bioorg. Med. Chem., 13(13), 4243-4252.@Yes$Vigorita M.G., Ottana R., Monforte F., Maccari R., Trovato A., Monforte M.T. and Taviano M.F. (2001).@Synthesis and anti-inflammatory, analgesic activity of 3,3&#8242;-(1,2-ethanediyl)-bis[2-aryl-4-thiazolidinone] chiral compounds.@Part10. Bioorg. Med. Chem. Lett., 11(21), 2791-2794.@Yes$Velmurugan V., Leelavathi N., Kalvikkarasi S., Shanmuga P.S. and Vijey A.M. (2012).@Synthesis and anticonvulsant activity of thiazolidinone derivatives.@International J. Chem. Tech. Res., 4(1), 1-4.@Yes$Ravichandran V., Prashantha Kumar B.R., Sankar S. and Agarwal R.K. (2009).@Predicting anti-HIV activity of 1,3,4-thiazolidinone derivatives: 3D-QSAR approach.@Eur. J. Med. Chem., 44(3), 1180-1187.@Yes$Bhat B.A., Ponnala S.K., Sahu D.P., Tiwari P., Tripathi B.K. and Srivastava A.K. (2004).@Synthesis and anti-hyperglycemic activity profiles of novel thiazolidinedione derivatives.@Bioorg. Med. Chem., 12(22), 5857-5864.@Yes$Kascheres C.M. (2003).@The chemistry of enaminones, diazocarbonyls and small rings: Our contribution.@J. Brazilian Chem. Soc., 14(6), 945-969.@Yes$Elassar A.Z.A. and El-Khair A.A. (2003).@Recent developments in the chemistry of enaminones.@Tetrahedron 59(43), 8463-8480.@Yes$Salama N.N., Eddington N.D., Payne D., Wilson T.L. and Scott K.R. (2004).@Multidrug resistance and anti-convulsant: New studies with some enaminones.@Curr. Med. Chem., 11(15), 2093-2103.@Yes$Edafiogho I.O., Kombian S.B., Ananthalakshmi K.V.V., Salma N.N., Eddington N.D., Wilson T.L., Alexander M.S., Jackson P.L., Hanson C.D. and Scott K.R. (2007).@Enaminones: Exploring additional therapeutic activities.@J. Pharma. Sci., 96(10), 2509-2531.@Yes$Levai A. (2004).@Synthesis of exocyclic &#945;, &#946;-unsaturated ketones.@ARKIVOC, (vii), 15-33.@Yes
@Short Communication
<#LINE#>Synthesis and characterization of complexes of 2-chloropyridine-3-carboxamide<#LINE#>Abdul @Wajid,R.B. @Mohod <#LINE#>45-48<#LINE#>7.ISCA-RJCS-2016-039.pdf<#LINE#>P.G. Department of Chemistry, Shri Shivaji College of Arts, Commerce and Science, Akola-444 003, MS, India@P.G. Department of Chemistry, Shri Shivaji College of Arts, Commerce and Science, Akola-444 003, MS, India<#LINE#>22/3/2016<#LINE#>3/12/2016<#LINE#>Certain metal complexes exhibit different characteristic properties depending on the nature of the metal as well as the type of ligand. The complexes of Mn(II), Co(II), Ni(II), Cr(III), Cu(II), Zn(II) and Cd(II) with the chelating ligand derived from 1-(2,4-dihydroxyphenyl) ethanone and 2-chloropyridine-3-carboxamide have been synthesized. The chelates have been characterized on the basis of elemental analyses, IR, 1HNMR, diffuse reflectance spectral and magnetic moment studies. The complexes are found to be colored and stable in air at room temperature. The structure of the ligands were elucidated by spectral studies which indicate the presence of two or three coordinating groups in ligands which may be oxygen atom of the phenolic -OH group, the nitrogen atom of the azomethine (C=N) group and the oxygen atom of the carbonyl group.<#LINE#>Harned H.S. and Owen B.B. (1950).@The Physical Chemistry of electrolyte solutions.@Food and agriculture Organization of the united nations.@Yes$Garnovskii A.D., Nivorozhkin A.L. and Minkin V.I. (1993).@Ligand environment and the structure of Schiff base adducts and tetracoordinated metal-chelates.@Coord. Chem. Rev., 126, 13-18.@Yes$Ettling C. (1840).@Untersuchungen über das ätherische Oel der Spiraea Ulmaria und die salicylige Säure.@Justus Liebigs Annalen der Chemie., 35, 241.@Yes$Kushwah N.P., Pal M.K., Wadawale A.P. and Jain V.K. (2009).@Diorgano-gallium and indium complexes with salen ligands: Synthesis, characterization, crystal structure and C–C coupling reactions.@J.Organomet. Chem., 694(15), 2375–2379@Yes$Andrez J.C. (2009).@Aromatic oxidative decompositions of copper Schiff base complexes.@Tetrahedron Lett., 50(29), 4225–4228.@Yes$Zhang Y., Xiang L., Wang Q. and Duan X.F. (2008).@G. Zi.@Inorg. Chim. Acta, 361, 1246.@Yes$Srinivasan K., Biravaganesh R., Gandhimathi R. and Ramasamy P. (2002)@Growth and characterization of NMBA (4-nitro-4&#8242;-methyl benzylidene aniline) single crystals.@J. Cryst. Growth, 236(1–3), 381–392.@Yes$Azariah A.N., Hameed A.S. H., Thenappan T., Noel M. and Ravi G. (2004).@Crystal growth and characterization of 4-nitro-4&#8242;-methoxy benzylidene aniline (NMOBA).@Mater. Chem. Phys., 88(1), 90–96.@Yes$Leela S., Ramamurthi K. and Bhagavannarayana G. (2009).@Synthesis, growth, spectral, thermal, mechanical and optical properties of 4-chloro-4&#8242;dimethylamino-benzylidene aniline crystal: A third order nonlinear optical material.@Spectrochim. Acta, 74(1), 78–83.@Yes$K. Nakamoto (1986).@Infrared and Raman spectra of Inorganic and Coordination Compounds.@, 4th ed., John Wiley and Sons.@Yes
<#LINE#>Methanolic extraction and isolation of bioactive chemicals from Pithecellobium dulce leaves by column chromatography and GC-MS studies<#LINE#>Anil @Bobade <#LINE#>49-52<#LINE#>8.ISCA-RJCS-2016-043.pdf<#LINE#>Department of Industrial Chemistry; Arts, Science and Commerce College, Chikhaldara, Amravati, MS-444807, India<#LINE#>22/3/2016<#LINE#>14/12/2016<#LINE#>Pithecellobium dulce is a species family Fabaceae, that is native to the India mostly Maharashtra area of Vidarbha. Pithecellobium dulce found secondary metabolism. It is used as medicinal plant. The methanolic extract of leaves was obtained by Soxhelt extractor followed by concentration in rotary evaporator. Separation of bioactive chemicals was carried out by column chromatography while studies by GC-MS which shows presence of following bioactive chemicals Squalene,9-Octadecenoic acid(Z)-,2-hydroxy-13propanediyl ester; 9 9-Octdecenoic acid,1,2,3-propanetriyl ester.<#LINE#>Grandtner Miroslav M. (2005).@Elsevier@1. Elsevier. 670–671.@Yes$Little E.L. and Wadsworth F.H. (1964).@Common trees of Puerto Rico and the Virgin Islands.@Agricultural Handbook. No. 249. US Department of Agriculture. Washington D.C.@Yes$Maria Jancy Rani J., Chandramohan G. and Renganathan R. (2012).@antioxidant activity, preliminary phytochemical investication and gc-ms Study of bougain villea glabra choicy leaves.@International Journal of Pharmacy and Pharmaceutical Sciences; 4(2), 12-16.@Yes$Laurence Dinana, Juraj Harmatha and Rene´Lafont (2001).@Chromatographic procedures for the isolation of plant steroids.@Journal of Chromatography, 935(1–2), 105–123.@Yes$Umesh Khandekar, Anil Bobade, Rahul Ghongade and Sachin Jolhe (2015).@Studies on Pharmacological and Chemical Composition of Crude Plant Extract of Rivea Hypocrateriformis.@Am. J. Pharm Tech Res.; 5(3), 297-306@No$Abirami P. and Rajendran A. (2002).@GC-MS analysis of methanol extract of Vernonia cinera.@European Journal Experiment biology, 2(1) 9-12 ,.@Yes$Smith Theresa J. (2000).@Squalene: potential chemopreventive agent.@Expert Opinion on Investigational Drugs. 9(8), 1841–1848.@Yes$Owen R.W., Haubner R., Würtele G., Hull W.E., Spiegelhalder B. and Bartsch H. (2004).@Olives and olive oil in cancer prevention.@European Journal of Cancer Prevention,13 (4), 319–26@Yes
<#LINE#>Chemical synthesis of cobalt oxide (Co3O4) nanoparticles using Co-precipitation method<#LINE#>K.F. @Wadekar,K.R. @Nemade ,S.A.@Waghuley <#LINE#>53-55<#LINE#>9.ISCA-RJCS-2016-055.pdf<#LINE#>Department of Physics, Sant Gadge Baba Amravati University, Amravati-444 602, India@Department of Physics, Sant Gadge Baba Amravati University, Amravati-444 602, India@Department of Physics, Sant Gadge Baba Amravati University, Amravati-444 602, India<#LINE#>22/3/2016<#LINE#>26/12/2016<#LINE#>In the present work, Cobalt oxide (Co3O4) nanoparticles were synthesized by co-precipitation method. The structural purity of as-prepared nanoparticles was confirmed by using X-Ray diffraction (XRD) analysis. The average particle size of amorphous structure of Co3O4 nanoparticles was found to be 25.62 nm and lattice parameter 7.97Å. The optical band gap of Co3O4 nanoparticles was estimated by using ultraviolet-visible (UV-VIS) spectroscopy. The direct band gap value was found to be 4.07eV. Photoluminescence (PL) spectroscopy was investigated two broad emission peaks at wavelength 396nm, 467nm of Co3O4 nanoparticles.<#LINE#>Moon J., Kim T.K., Saders B.V., Choi C., Liu Z., Jin S. and Chen R. (2015).@Black oxide nanoparticles as durable solar absorbing material for high-temperature concentrating solar power system.@Sol. Energ. Mat. Sol. C 134, 417–424.@Yes$Zheng Y., Li P., Li H. and Chen S. (2014).@Controllable Growth of Cobalt Oxide Nanoparticles on Reduced Graphene Oxide and its Application for Highly Sensitive Glucose Sensor.@Int. J. Electrochem. Sci., 9, 7369 – 7381.@Yes$Sun H., Ahmad M. and Zhu J. (2013).@Morphology-controlled synthesis of Co3O4 porous nanostructures for the application as lithium-ion battery electrode.@Electrochim Acta 89, 199 – 205.@Yes$Madhu R., Veeramani V., Chen S.M., Manikandan A., Lo A.Y. and Chueh Y.L. (2015).@Honeycomb-like Porous Carbon-Cobalt Oxide Nanocomposite for High-Performance Enzymeless Glucose Sensor and Supercapacitor Applications.@ACS Appl. Mater. Interfaces, 7(29):15812-20.@Yes$Cao Y., Yuan F., Yao M., Bang J.H. and Lee J. H. (2014).@A new synthetic route to hollow Co3O4 octahedra for supercapacitor applications.@Cryst. Eng. Comm, 16, 826–833.@Yes$Xu J.M., Zhang J., Wang B.B. and Liu F. (2015).@Shape-regulated synthesis of cobalt oxide and its gas-sensing property.@J. Alloys Compd. 619, 361–367.@Yes$Sahoo P., Djieutedjeu H. and Poudeu Pierre F.P. (2013).@Co3O4 Nanostructures: the effect of synthesis conditions on particles size, magnetism and transport properties.@J. Mater. Chem. A 1, 15022-15030.@Yes$Niasari M.S., Mir N. and Davar F. (2009).@Synthesis and characterization of Co3O4 nanorods by thermal decomposition of cobalt oxalate.@J. Phys. Chem. Solids, 70, 847–852.@Yes$Arciga-Duran E., Ballesteros J.C., Torres- Martinez L.M., Juarez - Ramirez I. and Gomez Solis C. (2005)@Co3O4 films prepared by thermal treatment of cobalt electrodeposited as an electrocatalyst for the oxygen evolution reaction.@J. Catal., 1-27.@No$Nandapure B.I., Kondawar S.B., Nandapure A.I. (2015).@Structural Characterization of Co3O4 Nanoparticles Synthesized By a Sol-Gel Method.@Int. J. Sci. Res.,4(1), 440-441.@Yes$Yarestani M., Khalaji A.D., Rohani A. and Das D. (2004).@Hydrothermal synthesis of cobalt oxide nanoparticles: Its optical and magnetic properties.@J. Sci. Islamic Republic Iran, 25(4), 339- 343.@Yes$Makhlouf S.A., Bakr Z.H., Aly K., Moustafa M.S. (2013).@Structural, electrical and optical properties of Co3O4 nanoparticles.@Superlattices and Microstructures, 64, 107–117.@Yes$Rathod P.B., Nemade K.R. and Waghuley S.A. (2015).@Study of Structure and Optical for Chemically Synthesized Titanium Dioxide Nanoparticles.@Int. J. Chem. Phys. Sci. 4, 491-95.@No$Farhadi Saeed, Sepahdar Asma and Jahanara Kosar (2013).@Spinel-Type Cobalt Oxide (Co3O4) Nanoparticles from the mer-Co (NH3)3(NO2)3 Complex: Preparation, Characterization and Study of Optical and Magnetic Properties.@J. nanostruct., 3(2), 199- 207.@Yes$Al-Tuwirqi R., Al-Ghamdia A.A., Aal N.A., Umar A. and Mahmoud W.E. (2011).@Facile synthesis and optical properties of Co3O4 nanostructures by the microwave route.@Superlattices and Microstruct, 49(4), 416–421.@Yes$Sarma H. and Sarma K.C. (2014).@X-ray Peak Broadening Analysis of ZnO Nanoparticles Derived by Precipitation method.@Int. J. Sci. Res. Publi., 4(3), 1-7.@Yes$Pejova B., Isahi A., Najdoski M. and Grozdanov I. (2001).@Fabrication and characterization of nanocrystalline cobalt oxide thin films.@Mater. Res. Bull., 36(1), 161–170.@Yes$Nemade K.R. and Waghuley S.A. (2013).@UV–VIS spectroscopic study of one pot synthesized strontium oxide quantum dots.@Res. Phys. 3, 52–54.@Yes
<#LINE#>Potentiometric titration of complexes with flavones and metal<#LINE#>T.S. @Bante,M.M. @Rathore ,P.R. @Rajput <#LINE#>56-57<#LINE#>10.ISCA-RJCS-2016-143.pdf<#LINE#>Department of Chemistry, Vidyabharti Mahavidyalaya, Amravati, MS, India@Department of Chemistry, Vidyabharti Mahavidyalaya, Amravati, MS, India@Department of Chemistry, Vidyabharti Mahavidyalaya, Amravati, MS, India<#LINE#>22/3/2016<#LINE#>28/3/2016<#LINE#>The dissociation constant and equivalence point in 70% Dioxane-Water and end point in different concentration with flavones at different temprature. Dissociation constant equivalence point has also calculated by potentiometer. Ligand had been studied using potentiometric method using calomel and platinum electrode various temperature for 0.1M ionic strength.<#LINE#>Desreux J.F., Merciny E. and Loncin M.F. (1981).@Nuclear Magnetic Resonance and Potentiometric studies of the Protonation Scheme of two Tetraaza Tetraacetic Macrocycles.@Department of analytical chem. and radiochemistry, university of liege, start tilman, B-4000 Belgium, Inorg.chem, 20(4), 987-991.@Yes$Tokiwa F. and Ohki K. (1966).@Potentiometric titration of a nonionic –cationic surfactant in aqueous solution.@The Journal of Physical Chemistry, 70(11), 3437-3441.@Yes$N.C. Lt. and E.D. (1951).@Complex Metal-amino acid complexes(&#921;&#921;) polarographic and potentiometric studies on formation, between copper (&#921;&#921;)  and amino acid ion 2000.@20.@No$Kawaguchi Y. and Nagasawa M. (1969).@Potentiometric titration of steroregular poly (acrylic acid).@The Journal of Physical Chemistry, 73(12), 4382-4384.@Yes$Rechnitz G.A. and Lin Z.F. (1968).@Potentiometric measurements with calcium-selective liquid membrane electrodes.@Analytical Chemistry, 40(4), 696-699.@Yes