@Research Paper
<#LINE#>N-[AMIDO] Substituted Pyrazole Compound used as Corrosive Inhibitor for Mild Steel in Acidic Environment<#LINE#>Warbhe@Priti,Deshmukh@Reshal <#LINE#>1-5<#LINE#>1.ISCA-RJCS-2016-001.pdf<#LINE#>Department of Chemistry, Shri Shivaji Science College, Congress Nagar, Nagpur-440012 MS, India@Department of Chemistry, Shri Shivaji Science College, Congress Nagar, Nagpur-440012 MS, India<#LINE#>6/1/2016<#LINE#>19/7/2016<#LINE#>The corrosion of metals and alloys in acidic medium is a world-wide scientific problem as it affects the various processes like metallurgical, chemical and oil industries. Thus, an inhibition action of 1-N amido 3-methyl 4[2-methoxy] phenyl amino 1, 2-pyrazole on corrosion of steel in acidic medium has been investigated by weight loss method. Result obtained reveals that presence of these compounds reduces corrosion rate. Corrosion action increases with the increase in concentration of pyrazoles compounds. The increase in temperature leads to decrease in the inhibition efficiency of the compounds.<#LINE#>Rao R.M., Reddy G.N. and Sreeramulu J. (2011).@Synthesis of some new pyrazolo -pyrazole derivatives containing indoles with antimicrobial activity.@Der Pharma Chemica, 3(5), 301-309.@Yes$Sharshira E.M. and Hamada N.M. (2011).@Synthesis and in Vitro Antimicrobial Activity of Some Pyrazolyl-1-carboxamide Derivatives.@Molecules, 16, 7736-7745@Yes$Siddique N.S., Idrees M., Khati N.T. and Dhonde M.C. (2013).@Synthesis and Antimicrobial Activities of Some New Pyrazoles, Oxadiazoles and Isoxazole Bearing Benzofuran Moiety.@South African Journal of Chemistry, 66, 7-11.@Yes$Mistry B.D., Desai K.R., Patel J.A. and Patel N.I. (2012).@Conventional and microwave assisted synthesis of pyrazole derivatives and screening of their antibacterial and antifungal activities.@Indian journal of chemistry, 51(B), 746-751.@Yes$Elenany M.M., EL-Meligie S.M., Abdou N.A. and EL-Nassan H.B. (2010).@Synthesis and antimicrobial activity of some 3,5-diaryl-4,5-dihydropyrazole derivatives.@Oriental Journal of Chemistry, 26(4), 1265-1270.@Yes$Rao R.M., Sreeramulu J., Ravindranath L.K., Reddy G.N., Hanumanthurayudu K., Reddy G.N., Jayaraju A and Madhusudhan P. (2012).@Synthesis and biological screening of some Pyridine and Pyrrole derivatives of Pyrazolo [3, 4-c] pyrazoles.@Journal of Chemical and Pharmaceutical Research, 4(1), 272-278.@Yes$Dabhi H.R., Rana A.K. and Parmar K.H. (2014).@Synthesis, characterization and antimicrobial screening of some novel Heterocyclic compounds derived from chalcone.@Pelagia Research Library Der Chemica Sinica, 5(6), 64-68.@Yes$Kedar R.M. (2001).@Synthesis of 1- Carboxamido- 3, 5 Diaryl- Pyrazolines and their Antimicrobial Study.@Asian Journal of Chemistry, 13(2), 477-480.@Yes$Herrag L., Chetouani A., Elkadiri S., Hammouti B. and Aouniti B. (2008).@Pyrazole Derivatives as Corrosion Inhibitors for Steel in Hydrochloric Acid.@Portugaliae Electrochimica Acta, 26, 211-220.@Yes$Ezhilarasi M.R., Prabha B. and Santhi T (2015).@Pyrazole Methyl Substituted Compound used as a Corrosive Inhibitor for Mild Steel in Acidic Environment.@Research Journal of Chemical Sciences, 5(5), 1-12.@No$Eno E. Ebenso, Ime B. Obot and Murulana L.C. (2010).@Quinoline and its Derivatives as Effective Corrosion Inhibitors for Mild Steel in Acidic Medium.@Int. J. Electrochem. Sci., 5, 1574-1586.@Yes$Al-Doori H.H. and Mehdi S. Shihab. (2014).@Study of Some [N-substituted] p-aminoazobenzene as Corrosion Inhibitors for Mild-Steel in 1M H2SO4.@Journal of Al-Nahrain University, 17(3), 59-68.@Yes$Yaro A.S. and Dhuha A. Abdulaaima (2012).@Phenyl Thiourea as Corrosion Inhibitor for Mild Steel in Strong Hydrochloric Acid.@Iraqi Journal of Chemical and Petroleum Engineering, 13(2) 1-9.@Yes$Ghazoui A., Saddik R., Benchat N, Guenbou M., Hammouti B.,  Al-Deyab S.S. and Zarrouk A. (2012).@Comparative Study of Pyridine and Pyrimidine Derivatives as Corrosion Inhibitors of C38 Steel in Molar HCl.@Int. J. Electrochem. Sci., 7, 7080-7097.@Yes$Fouda A.S., Rashwan S. and ElghazyY.K. (2013).@Methyl Orange as Corrosion Inhibitor for Carbon Steel in Hydrochloric Acid Solutions.@International Journal of Advanced Research, 1(10), 568-589.@No$Edrah S. and Hasan S.K. (2010).@Studies on Thiourea Derivatives as Corrosion Inhibitor for Aluminium in Sodium Hydroxide Solution.@Journal of Applied Sciences Research, 6(8), 1045-1049.@Yes
<#LINE#>Synthesis of (-) Baclofen as a Neurotransmitter Inhibitor<#LINE#>Lokhande@Mahendra N. ,Bhangare@Dattatraya N.,Kapse@Omkar K. ,Nikalje@Milind D.<#LINE#>6-9<#LINE#>2.ISCA-RJCS-2016-040.pdf<#LINE#>Department of Chemistry, MNG Science College Babhulgaon-445101, India@Department of Chemistry, Savitribai Phule University of Pune-411007, India@Department of Chemistry, MNG Science College Babhulgaon-445101, India@Department of Chemistry, Savitribai Phule University of Pune-411007, India<#LINE#>22/3/2016<#LINE#>18/7/2016<#LINE#>Here, we reports enantioselective Michael additions reaction of diethyl malonate with substituted styrene. The yield ranges from 80-65 % having enantioselectivity 80-95%. The present strategy useful for the synthesis (-)-Baclofen. Starting from commercially available 4-chlorobenzaldehyde.<#LINE#>Kristina Wilckens, Marcel-Antoine Duhs, Dieter Lentz and Czekelius Constantin (2011).@Chiral 1,1_-Bi(tetrahydroisoquinoline)-Type Diamines as Efficient Ligands for  Nickel-Catalysed Enantioselective Michael Addition to Nitroalkenes.@Eur. J. Org. Chem., (28), 5441-5446.@Yes$Tsubasa Inokuma, Masaya Furukawa, Takuya Uno, Yusuke Suzuki, Kohzo Yoshida, Yoshiaki Yano, Katsumi Matsuzaki and Takemoto Yoshiji (2011).@Bifunctional Hydrogen-Bond Donors That Bear a Quinazoline or Benzothiadiazine Skeleton for Asymmetric Organocatalysis.@Chem. Eur. J., 17(37), 10470-10477.@Yes$Jin-ming Liu, Xin Wang, Ze-mei Ge, Qi Sun, Tie-ming Cheng and Run-tao Lii (2011).@Solvent-free organocatalytic Michael addition of diethyl malonate to nitroalkenes: the practical synthesis of Pregabalin and &#947;-nitrobutyric acid derivatives.@Tetrahedron, 67(3), 636-640.@Yes$Laurence Menguy and Francois Couty (2010).@Azetidine-derived bifunctional organocatalysts for Michael reactions.@Tetrahedron: Asymmetry., 21(19), 2385-2389.@Yes$Diana Alma&#351;i, Diego A. Alonso, Enrique Gómez-Bengoa and Carmen Nájera. (2009).@Chiral 2-Aminobenzimidazoles as Recoverable Organocatalysts for the Addition of 1,3-Dicarbonyl Compounds to Nitroalkenes.@J. Org. Chem. 74(16), 6163-6168.@Yes$Patrick G. McGarraugh and Stacey E. Brenner. (2009).@Novel bifunctional sulfonamides catalyze an enantioselective conjugate addition.@Tetrahedron., 65(2), 449-455.@Yes$David A. Evans, Shizue Mito, Daniel Seidel (2007).@Scope and Mechanism of Enantioselective Michael Additions of 1,3-Dicarbonyl Compounds to Nitroalkenes Catalyzed by Nickel(II)&#8722;Diamine Complexes.@J. Am. Chem. Soc., 129(37), 11583-11592.@Yes$Alessandra Lattanzi. (2006).@Enantioselective Michael addition of malonate esters to nitroolefins organocatalyzed by diaryl-2-pyrrolidinemethanols.@Tetrahedron: Asymmetry. 17(5) 837-841.@Yes$Masahiro Terada, Hitoshi Ube and Yusuke Yaguchi (2006).@Axially Chiral Guanidine as Enantioselective Base Catalyst for 1,4-Addition Reaction of 1,3-Dicarbonyl Compounds with Conjugated Nitroalkenes.@J. Am. Chem. Soc., 128(5), 1454.@Yes$Tomotaka Okino, Yasutaka Hoashi, Tomihiro Furukawa, Xuenong Xu and Yoshiji Takemoto (2005).@Enantio- and Diastereoselective Michael Reaction of 1,3-Dicarbonyl Compounds to Nitroolefins Catalyzed by a Bifunctional Thiourea.@J. Am. Chem. Soc., 127(1), 119.@Yes$Jinxing Ye, Darren J. Dixon, Peter S. Hynes (2005).@Enantioselective organocatalytic Michael addition of malonate esters to nitro olefins using bifunctional cinchonine derivatives.@Chem.comm, 35, 4481-4485.@Yes$Hongming Li, Yi Wang, Liang Tang, Li Deng (2004).@Highly Enantioselective Conjugate Addition of Malonate and &#946;-Ketoester to Nitroalkenes: Asymmetric C&#8722;C Bond Formation with New Bifunctional Organic Catalysts Based on Cinchona Alkaloids.@J. Am. Chem. Soc. 126(32), 9906-9907.@Yes
<#LINE#>Synthesis and Characterization of Macrocycles Derieved from Bis-Triazole<#LINE#>Barabde@Jagruti M.,Ghatole@Pranali D. <#LINE#>10-14<#LINE#>3.ISCA-RJCS-2016-068.pdf<#LINE#>Department of Chemistry, Sant Gadge Baba Amravati University, Amravati-444 602, (MS) India@Department of Chemistry, Sant Gadge Baba Amravati University, Amravati-444 602, (MS) India<#LINE#>22/3/2016<#LINE#>7/7/2016<#LINE#>The new macrocyclic Schiff bases were obtained by condensing the 5,5\'-(butane-1,4-diyl)bis(4-amino-4H-1,2,4-triazole-3-thiol) with the corresponding dialdehyde. The dialdehydes needed for the macrocycles were synthesized by using substituted hydroxyl aldehyde, which was converted into its potassium salt and treated with appropriate dibromoalkane to afford the corresponding dialdehyde. All the synthesized compounds were characterized by IR,1H-NMR, mass and some of the representative by 13C-NMR spectra.<#LINE#>Rednic M.I., Hadade N.D. and Grosu E.B.I. (2015).@Macrocycles embedding phenothiazine or similar nitrogen and/or sulphur containing heterocycles.@J. Incl. Phenom. Macrocycle Chem., 81(3), 263-293.@Yes$Khalaji A.D., Ghoran S.H., Rohlicek J. and Dusek M. (2015).@Characterization and crystal structure of a 17-membered macrocyclic Schiff base compound MeO-sal-pn-bn.@J. struct chem.,56(2), 259-265.@Yes$Foroughifar N., Mobinikhaledi A. and Ebrahimi S. (2009).@Synthesis of a Novel Class of Azacrown Macrocycles and Lariat Crown Ethers Containing Two 1,2,4-Triazole Rings as Subunits.@Synthesis, 15, 2557-2560.@Yes$Potts K.T. (1961).@The Chemistry of 1,2,4-Triazoles.@Chem. Rev., 61(2), 87-127.@Yes$Agalave S.G., Maujan S.R. and Pore V.S. (2011).@Click Chemistry: 1,2,3-triazole as pharmacophore.@J.Chem. Asian., 6(10), 2696-2718.@Yes$Kane J.M., Baron B.M., Dudley M.W., Sorensen S.M., Staeger M.A. and Miller F.P. (1990).@2,4-Dihydro-3H-1,2,4-triazol-3-ones as anticonvulsant agents.@J.Med.Chem., 33(10), 2772-2777.@Yes$Noblia P., Vieites M., Parajon-Costa B.S., Baran E.J., Cerecetto H., Draper P., Gonzalez M., Piro O.E., Castellano E.E., Azqueta A., Cerain A.L. and Gambino A.D. (2005).@Vanadium (V) complexes with salicylaldehyde semicarbazone derivatives bearing in vitro anti-tumor activity toward kidney tumor cells (TK-10): crystal structure of [VVO2(5-bromosalicylaldehyde semicarbazone)]@J. Inorg. Biochem., 99(2),  443-451.@Yes$Zitouni G.T., Kaplancikli Z.A., Erol K., Kilic F.S. (1999).@Synthesis and analgesic activity of some triazoles and triazolothiadiazines.@II Farmaco, 54(4), 218-223.@Yes$Khalil N.S.A.M. (2010).@Efficient synthesis of novel 1,2,4-triazole fused acyclic and 21-28 membered macrocyclic and/or lariat macrocyclic oxaazathia crown compounds with potential antimicrobial activity.@Eur.J.med.chem., 45(11), 5265-5277.@Yes$Abbas A. A. (2004).@Synthesis of novel lariat azathia crown macrocycles containing two triazole rings and bis crown macrocycles containing four triazole rings.@Tetrahedron, 60(7), 1541-1548.@Yes$Xu P.F., San X-W., Zang L.M. and Zang Z.Y. (1999).@A Facile Synthesis of Bis(4-amino-5-mercapto-1,2,4-triazol-3-yl)alkanes and Bis(5-mercapto-4H-1,2,4-triazol-3-yl)alkanes.@J. chem. Research.,(2), 170-171.@Yes$Pellisard D. and Luis R. (1972).@Ligands macrocycliques pentadendates.@Tetrahedron Lett., 13(45), 4589-4593.@Yes$Overman L.E. (1972).@Dehydrogenase Enzyme Models. Approximation of an Alcohol and a Pyridinium Ring.@J.org.chem., 37,  4214-4218.@Yes
<#LINE#>Reverse Phase High Performance Liquid Chromatography method for Simultaneous Determination of Ofloxacin and Ornidazole in Pharmaceutical Dosage<#LINE#>Rele@Rajan V.,Sawant@Swapnil A. <#LINE#>15-19<#LINE#>4.ISCA-RJCS-2016-140.pdf<#LINE#>Central Research Laboratory, D.G. Ruparel College, Matunga, Mumbai 400016, India@Central Research Laboratory, D.G. Ruparel College, Matunga, Mumbai 400016, India<#LINE#>22/3/2016<#LINE#>29/7/2016<#LINE#>For validation of ofloxacin and ornidazole from its combined pharmaceutical formulations a reverse phase high pressure liquid chromatography method is proposed. Resolution was carried out on Waters Symmetry shield C8 column. A mobile phase composed of acetonitrile and buffer (18:82% (v/v). Wavelength 280 nm was used for detection. The ICH guidelines was applied for study of different parameters. The proposed method is easily and successfully applied to analyze ofloxacin and ornidazole from pharmaceutical combined formulations.<#LINE#>British Pharmacopoeia (2003).@Licensing division HMSO.@Norwich, 357.@Yes$United States Pharmacopoeia (2004).@United States Pharmacopoeial Convention, Inc.@Rockville,  1335.@No$European Pharmacopoeia (2005).@EDQM, Council of Europe, Strasbourg, France.@5th Ed, 2131.@No$Bhusari K.P. and Chaple D.R. (2009).@Simultaneous Spectrophotometric Estimation of ofloxacin and ornidazole in Tablet dosage Form.@Asian J. Research Chem, 2(1), 60-62.@Yes$Kasture V.S., Bhagat A.D., Puro N.C., More P.S. and Bhandari N.K. (2004)@Spectrophotometric method for simultaneous estimation of ofloxacin and ornidazole in tablet dosage form.@Indian Drugs, 41, 51-53.@Yes$Ganhimathi M., Ravi T.K. and Shukla N. (2006).@Validated high performance thin layer chromatography method for simultaneous estimation of ofloxacin and ornidazole.@Indian J.  Pharm. Sci., 68, 838-840.@Yes$Ghosh Soumya Jyoti, Darbar Soumendra, Chowdhury Partha Pratim, Chattopadhyay Shyama Prasad, Chakraborty Matish Ranjan (2010).@Simultaneous Determination and Validation of Ofloxacin and Ornidazole in Combined Dosage Pharmaceutical Formulation.@International Journal of Pharm Tech Research, 2(1), 367-374.@Yes$Nalini C.N., Ramachandran S., Kavitha K. and Harikrishna (2011).@Simultaneous Determination of of loxacin and ornidazole in Tablets by spectrophotometry and reverse phase HPLC.@Research Journal of Pharmaceutical, Biological and Chemical Sciences, 2(3), 693-708.@No$Miniyar Pankaj B., Mulani Afroj, Dhange Anup A, Gawande Vandana T and Kashid Arun M (2012).@Development and Validation of RP-HPLC Method for Simultaneous Determination of Ofloxacin and Ornidazole In Infusion.@Am. J. PharmTech Res, , 2(5), 382-390.@Yes$Dhandapani B., Thirumoorthy N., Shaik Harun Rasheed, kotaiah M.Rama and Anjaneyalu N. (2010).@Method development and validation for the simultaneous estimation of ofloxacin and ornidazole in tablets dosage form by RP-HPLC.@International Journal of Pharma Sciences and Research, (1), 78-83.@Yes$Puranik Manisha, Bhawsar D.V., Rathi Prachi and Yeole P.G. (2010).@Simultaneous Determination of Ofloxacin and ornidazole in Solid Dosage Form by RP-HPLC and HPTLC Techniques.@Indian J. Pharm. Sci., 72(4), 513-517.@Yes$Budavari S. Eds. In. (2001).@The Merck Index.@Merck & co., Inc. Whitehouse Station, NJ. 13th   Ed, 1213-1229.@No$Mehta Saumil, Singh Sukhdev, Chikhalia Kishor, Shah Vishal and Saraswat Girish (2012).@Simultaneous estimation of Ofloxacin and ornidazole in combined dosage forms by dual wavelength and ratio Spectra Derivative Methods using UV-Spectrophotometer.@International Journal of PharmTech Research, 4(3), 975-985.@Yes
<#LINE#>Levels of Heavy Metals in the Effluents of Forcados Terminal from Delta State<#LINE#>Ebele@Amaku Grace,Chimezie@Anyanwu Jonathan <#LINE#>20-23<#LINE#>5.ISCA-RJCS-2016-167.pdf<#LINE#>Department of Environmental Technology, Federal University of Technology Owerri, Imo State, Nigeria@Department of Environmental Technology, Federal University of Technology Owerri, Imo State, Nigeria<#LINE#>19/4/2016<#LINE#>29/7/2016<#LINE#>Levels of heavy metals in the effluent samples from Forcados Terminal in Warri, Delta State were studied from May 2008 to June 2009. Effluent samples were collected from the two Barge Jetties A and B and Two Saver Pits 1 and 2 inside the tank farm. A total of 96 effluent samples were collected throughout the study period. The levels of heavy metals of the effluent samples were determined using Hach methods as recommended by the American Public Health Association (APHA) and American Society for Testing and Material (ASTM). The results of the heavy metals tested showed that most of the parameters tested complied with their respective DPR and FEMENV Limits for nearshore environments. There was statistical difference at p &#8804; 0.05 in the levels of heavy metals analysed. The range of values obtained for heavy metalsanalysedwere, 0.02-3.89 mg/l for Cu, 0.004 – 3.64 mg/l for Fe, 0.001 – 1.44 mg/l for Zn, 0.001 - 0.63mg/l for Ni. Lead, Mercury and Cadmium were present at levels below detectable limit in almost all the samples anaylsed. Most of the parameters tested for complied with their respective DPR limits for near-shore environments. Periodic monitoring should be given to the Forcados Treatment plants in order to maintain their efficiency.<#LINE#>Hogan C.M. (2010).@Heavy metal. Encycolopedia of Earth. National council for science and the environment.@Washington DC.@Yes$Duffus J.H. (2002).@Heavy metals term (IUPAC Technical report).@Pure and Applid Chemistry, 74, 793-807.@Yes$Adeyinka J.S. (1996).@Waste water treatment through reverse osmosis.@Env. Monitoring and Assessment. 22 – 37.@Yes$Kakulu S.E. and Osibanjo O. (1991).@Pollution Studies of the Nigerian Rivers Trace metal levels of surface water in the Niger Delta area.@Int’l. J. Environ. Stud. Anal. Chem., 30, 209-217.@Yes$APHA (2002).@Standard methods for the examination of water and waste water.@20th Ed. American public health association (APHA).@Yes$ASTM E. (1986).@American Society for Testing and Materials.@Annual Book of ASTM Standards, 11.01, Philadelphia PA 19103, D 3559-85.@No$Zhenbin Li and Larry M. Shuman (1996).@Heavy metals movement in metal contaminated soil profiles.@Soil Sci., 10, 656-666.@Yes$Horsefall M. Jnr., Spiff I.A. (1998).@Principles of Eviron.@Chem. Metroprints Ltd, Port Harcourt, Nigeria, 30-62.@No$Neff J.M. (2001).@Bioaccumulation in Marine Organisms. Effect of Contaminants from Oil Well Produced Water.@Batelle Coastal Resources and Environmental Management, Duxbury, Massachusetts.@Yes$Newman M.G. and Jagoe C.H. (1994).@Ligands and the bioavailability of metals in aquatic environments.@Homelink, J.L., Landrum, P.F., Bergman, H.L and  Benson W.H. (eds). Bioavailability: Physical, Chemical and Biological interactions. Lewis publishers, Boca Raton, FL, 396, 39-61.@Yes
<#LINE#>Variation of Global Solar Radiation at different altitudes of Mid-Western Region, Nepal<#LINE#>Bed Raj @K.C.,Khem N.@Poudyal,Gurung@Shekhar <#LINE#>24-28<#LINE#>6.ISCA-RJCS-2016-179.pdf<#LINE#>Mahendra Multiple Campus, Tribhuvan University, Nepalganj, Nepal@Institute of Engineering, Tribhuvan University, Kathmandu, Nepal@Central Department of Physics, Tribhuvan University, Kathmandu, Nepal<#LINE#>16/5/2016<#LINE#>20/7/2016<#LINE#>The experimental results on global solar radiation in some locations in Nepal measured by calibrated pyranometer at Jumla(29.27°N to 82.18°E, 2514.0m), Dang (28.70°N, 82.18°E, 603.0m) and Nepalgunj (28.05°N, 81.62°E, 150.0m) since 2011. The influence of different meteorological as well as physical parameters to the intensity of global solar radiation was analyzed. This research highlighted fluctuation of the measured value of global solar radiation with local weather condition.  Measured global solar radiation data shows that there is about 7.5% per km increase in Jumla in comparision with Dang and Nepalgunj. This result conformed that there is strong correlation found in between altitude and global solar radiation. In addition the GSR varies with environmental pollution and local weather condition.<#LINE#>Shashaank Shekhar I.P. (2012).@Direct Normal irradiance.@New Delhi: Compendium of National Training Programme On RETScreen International Software for Evaluationof Renewable Energy Projects.@No$WECS (2010).@Water Energy Commission Secretariat.@Energy sector Synopsis Report.@No$Kerr J.B. (2003).@Understanding the factors for affect surface UV radiation.@Ultraviolet Ground andspace based measurements,Model, and effects, 1-14.@Yes$Salby M. (1996).@Fundamentals of Atmospheric Physics.@61, International Geophysics Series, Academic Press.@Yes$Seckmeyer G.E. (1996).@Transmittance of a cloud is wavelength dependent in UV Range.@Geophys, Res, Lett., 23(20), 2753-2755.@Yes$RECAST TU. (2001).@Development of Solar Dryers in Nepal.@10-11.@No$Thapa M.K., Bhattarai B.K.,Gurung S.,Sapkota B.K. and poudyal K.N.(2016).@Diurnal and Monthly Variation of Aerosol optical Depth and Angstrom@Research Journal of Chemical Sciences Volume, 6(2), 40-44.@No$Barry R.G. and Chorley R.J. (1978).@Atmosphere, Weather and Climate.@40-41.@Yes$WMO (2003).@Scientific Assessment of Ozone depletion.@Global Ozone research and Monitoring Project Report, 47.@No$Schmucki. D.A. and Philipona Rolf (2002).@Ultraviolet radiation in the Alps:the altitude effect.@Opt. Eng., 41, 5369-5383.@Yes$Poudyal K.N., Bhattarai B.K., Sapkota B. and Kjeldstad Berit (2012).@Estimation of Global solar Radiation using Sunshine duration in Himalaya Region.@Research Journal of Chemical Sciences, 2(11), 20-25.@Yes$Kipp and Zonen (2008).@CMP series instruction manual.@Kipp and Zonen B.V., Delftech park 36, Netherlands.@No
<#LINE#>Chemical Assessment of Different Brands of Commercial table Salts Sold in Sokoto Central Market, Sokoto<#LINE#>Uba@A.,Abdullahi@M.I.,Yusuf@A.J.,Nasir@I.,Ibrahim@Z.Y.Y.,Yahaya@M.,Umar@A. <#LINE#>29-35<#LINE#>7.ISCA-RJCS-2016-186.pdf<#LINE#>Department of Pharmaceutical and Medicinal Chemistry, Usmanu Danfodiyo University, Sokoto, Nigeria@Department of Pharmaceutical and Medicinal Chemistry, Usmanu Danfodiyo University, Sokoto, Nigeria@Department of Pharmaceutical and Medicinal Chemistry, Usmanu Danfodiyo University, Sokoto, Nigeria@Department of Pharmaceutical and Medicinal Chemistry, Usmanu Danfodiyo University, Sokoto, Nigeria@Department of Pharmacognosy and Ethnopharmacy, Usmanu Danfodiyo University, Sokoto, Nigeria@Department of Pure and Applied Chemistry, Usmanu Danfodiyo University, Sokoto, Nigeria@Department of Pure and Applied Chemistry, Usmanu Danfodiyo University, Sokoto, Nigeria<#LINE#>7/6/2016<#LINE#>16/7/2016<#LINE#>Table salt is the most common food additive used by a large number of people. Hence, if adulterated, it could pose a serious threat to public health. The present study was aimed at quantitatively and qualitatively assessing five different brands of commercial table salts (TS-1 – TS-5) sold in Sokoto Central Market. The qualitative analysis of each sample was conducted using standard procedures. The level of sodium (Na), potassium (K), copper (Cu), manganese (Mn) and Iron (Fe) was determined using flame photometer and atomic absorption spectroscopy. The results obtained for the salts samples showed that the density values ranges from 2.20 – 2.60 g/cm3 while the moisture content was generally low having 0.50 % but TS-5 had 10.5 %. The solubility value for the salt samples fall within the range of 7.37 – 12.65 g/100g which was thrice the solubility of TS-5 (2.53 g/100g). The degree of hydrosorption for the salt samples were within the range 3.65 – 3.97 g and the conductivity values ranges from 7.11 × 10-2 - 7.11 × 10-2. The pH value of the samples were alkaline having 7.04 – 10.21 and SO42-, Cl-, I- were present in all the samples except for TS-4 which do not contain SO42-. The levels of Na, K, Mn and Fe for most of the salt samples were found to fall within the permissible limit of World Health Organization (WHO) and Cu was not detected in the samples.<#LINE#>Desrosie N.W (1977).@Elements food Technology.@The AVI publishing company Inc, West port Connecticut, 20, 200 and 300. Bloch (2006). Economics of sodium chloride, salt made the world go round. Journal of Science, 20, 200 and 310.@No$Hurlbut Cornelius S. (1985).@Manual of Mineralogy.@20th ed., John Wiley and Sons, New York ISBN 0-471-80580-7.@Yes$Laszlo Pierre (2001).@Salt grain of life.@Arts and tradition of the table salt.@Yes$Standard organization of Nigeria (SON) (1992).@Standard for food grade salt.@NIS 168.@No$Lindberg W. (1992).@A suggestion for the terminology of certain mineral deposits Economic Geology.@Australian Journal of Geology 8, 69-78.@Yes$Al-Eed M.A., Assubaie F.N., El-Garawany M.M., ELHamshary H. and ElTayeb Z.M. (1997).@Determination of Heavy Metal Levels in Common Spices.@J. Agric. Sci. Mansoura Univ.7. 22 (5): 1685-1692.@Yes$Cabrera C., Lorenzo M.L. and Lopez C.M. (1995).@Lead and cadmium contamination in dairy products and its repercussion on dietary intake.@J. Agri. Food Chem., 43, 1605-1609.@Yes$Jahed Khaniki G.R., Dehghani M.H., Mahvi A.H. and Nazmara S. (2007).@Determination of Trace Metal Contaminants in Edible Salts in Tehran (Iran) by AtomicAbsorption Spectrophotometry.@Journal of Biological Sciences, 7, 811-814.@Yes$Cheraghali A.M., Kobarfard F. and Faeizy N. (2010).@Heavy metals contamination of tablesalt consumed in iran.@Iranian journal of pharmaceutical research. 9(2), 129-32.@Yes$Zarei M., Eskandari M.H. and Pakfetrat S. (2011).@Determination of Heavy Metals Content of Re&#64257;ned Table Salts.@American-Eurasian Journal of Toxicological Sciences, 3(2), 59-62.@Yes$Zukowska J. and Biziuk M. (2008).@Methodological Evaluation of Method for Dietary Heavy Metal Intake.@Journal of Food Science, 73(2), 21-29.@Yes$Gupta K.K., Bhattacharjee S., Kar S., Chakrabarty S., Thakar P, Bhattacharyya G. and Srivastava S.C. (2003).@Mineral composition of eight common spices.@Comm. Soil Plant Anal., 34: 681-693.@Yes$Ansari T.M., Ikram N., Najam-ul-Haq M., Fayyaz O., Ghafoor I. and Khalid N. (2004).@Essential trace metal (Zn, Mn, Cu, and Fe) levels in plants of medicinal importance.@J. Biol. Sci, 95-99.@Yes$Birnin yauri U.A. and Abubakar Z. (1999).@Investigation of the chemical content of commercial cooking salts.@Nigeriajournal of Basic and Applied Science, 8, 71-75.@Yes$Horwitz W. and Horwitz W. (2000).@Official method of Analysis.@Association of official Analytical chemists, Arlington, V.A, USA.@No$Horwitz W. et. al. (1970).@Official methods of analysis of the Association of Official Analytical Chemists.@11th Editon.Washington D.C.@Yes$Wolfram K. and  Holthausen M.C. (2001).@A Chemist@2nd Edition, 313, ISBN: 978-3-527-30372-4@Yes$Bassetts J., Denny R.C., Jeffery D.H. and Mendham J.  (1978).@Vogel’s Quantitative ingorganic Analysis (4th ed).@Longman Group Limited, London, 725-745.@No$Blaurockbusch E. (1996).@Mineral and trace element analysis.@BoulderCO.TMI/MTM BOOKS.@No$Agasyam P.K. (1980).@Qualitative Chemical semi MicroAnalysis.@(Translated by Artavaz B.0) Mir publishers Moscow, 124-478.@Yes$Yusuf A.J., Galadima A., Garba Z.N and Nasir I (2015).@Determination of some Heavy metals in Soil sampl from Illela Garage in Sokoto State, Nigeria.@Research journal of Chemical Sciences.@Yes$Diosady L.L., Alberti J.O., Venkatesh Mannar M.G. and FitzGerald S. (1998).@Stability of Iodine in iodized salt used for correction of iodine-deficeiency disorders II.@Food Nutri Bull., 18, 240-250.@Yes$Biber J., Malmström K., Scalera V. and Murer H. (1983).@Phosphorylation of rat kidney proximal tubular brush border membranes, Role of cAMP dependent protein phosphorylation in the regulation of phosphate transport.@Pflügers Arch. 398, 221–226.@Yes$Khan N.A., Syeed S., Masood A., Nazar R. and Iqbal N. (2010).@Application of salicylic acid increases contents ofnutrients and antioxidative metabolism in mungbean and alleviatesadverse effects of salinity stress.@International Journal of PlantBiology, 1(1), 1-8.@Yes$Sumithra Na E. and Johnson A. (2015).@Salt craving: The psychobiology of pathogenic potassium intake.@Physiol Behave, 94, 709-721.@No$Wang D., Du X. and Zheng W. (2008).@Alteration of saliva and serum concentrations of manganese, copper, zinc, cadmium and lead among career welders.@Toxicol Lett., 176, 40-47.@Yes$Beard J.L. (2001).@Iron biology in immune function, muscle metabolism and neuronal functioning.@J Nutri, 131, 568S-579S.@Yes$James D.C. (2005).@Diagnosis and management of iron deficiency anemia.@Best Practice Res Clin Haemato, 18, 319-332.@Yes$Morris C.D., Jacobson S.L., Annand R., Ewell M.G., Hauth J.C., Curret L.D., Catalano P.M., Sabai B.M. and Leveine R.J. (2001).@Nutrient intake and hypertensive disorders of pregnancy; Evidence from large prospective cohort.@Am J. Obstet Gynecol., 184, 643-651.@Yes$Raisbeck M.F., Rker C.S., Tate R.C., Jackson M.R., Smith K.M., Reddy K. and J. Zygmunt J. (2008).@Water Quality for Wyoming livestock and Wildlife.@A Review of the Literature pertaining to Health Effects of Inorganic Contaminants.@Yes$Pretzer S.D. (2000).@Diarrhea in gilts caused by excessive dietary sodium chloride.@Swine Health Prod., 8(4), 181-183.@Yes$Gary Taubes (1998).@The political science of salt”, Journal of Science.@281, 5379, Hurl But and Cornelius (1985). “Manual of mineralogy. 20th edition, John Wiley and sons, New York ISBN 0-471-80580-7.@Yes$Vogel A.I. (1989).@Quantitative Chemical Analysis.@5thEdition, Longman Scientific & Technical, John Willey & Sons Inc., New York. ISBN-0-582-44693-7.@Yes
<#LINE#>Amino Phenolic AZO Compounds Synthesis and Bilogical Analysis<#LINE#>Shelke@Namrata S. ,Thakare@N.S. <#LINE#>36-42<#LINE#>8.ISCA-RJCS-2016-187.pdf<#LINE#>Department of Chemistry, M. S. P. College, Manora, India@Department of Chemistry, M. S. P. College, Manora, India<#LINE#>15/6/2016<#LINE#>29/7/2016<#LINE#>The diazotization reaction pathway has been used for the synthesis of several azo compounds. This synthesis consists of amino phenol. The resultant products are characterized by FTIR / 1H NMR spectroscopy method.  These products show excellent antimicrobial behavior.<#LINE#>Kirkan B. and Gup R. (2008).@Synthesis of new azo dyes and copper (II) complexes derived from barbituric acid and 4-aminobenzoylhydrazone.@Turk. J.Chem., 32, 9-17.@Yes$Sakong C., Kim Y.D., Choi J.H., Yoon C. and Kim J.P. (2011).@The synthesis of thermally-stable red dyes for LCD color filters and analysis of their aggregation and spectral properties.@Dyes Pigment, 88, 166-173.@Yes$Hunger K. (2003).@Industrial Dyes: Chemistry, Properties, Applications.@WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim, 58-66.@Yes$Patel D.G. and Prajapati N.K. (2012).@Formation Of Some Novel Acid Azo Dyes: Synthesis, Characterisation & Application Properties.@Asian J. Biochem. Pharm. Res., 2, 255-261.@Yes$Ahmad Thawra, Kandil Farouk and Moustapha Chahid (2015).@Preparation and Characterization of Some New Azo Dyes, Azomethine Dyes and Heterocyclic-Schiff Bases Derivatives.@AASCIT Journal of Chemistry, 24-31.@No$Zarei M. and Mohamadzadeh M. (2011).@3-Thiolated 2-azetidinones: synthesis and in vitro antibacterial and antifungal activities.@Tetrahedron, 67(32), 5832-5840.@Yes
@Short Communication
<#LINE#>Thermal Conductivity Enhancement in Zinc Oxide-Water Based Nanofluid System<#LINE#>Nemade@Kailash,Varade@Vikas,Waghuley@Sandeep <#LINE#>43-45<#LINE#>9.ISCA-RJCS-2016-072.pdf<#LINE#>Department of Physics, Indira Mahavidyalaya, Kalamb 445 401, India@Department of Physics, Sant Gadge Baba Amravati University, Amravati 444 602, India@Department of Physics, Sant Gadge Baba Amravati University, Amravati 444 602, India<#LINE#>22/3/2016<#LINE#>15/7/2016<#LINE#>Through this research article, we report our primary work of Zinc Oxide-Water (ZnO-H2O) based nanofluid indicating increase in heat transfer as a function of concentration of ZnO nanoparticles. The main objective of present is to analyze effect of nanoparticles concentration on thermal conductivity of nanofluid. The enhancement in heat transfer of nanofluid was observed with concentration, but in irregular manner. The irregularity in enhancement of thermal conductivity is discussed using orthokinetic aggregation effect. The thermal conductivity ratio of ZnO-H2O based nanofluid suggest that as-prepared nanofluids exhibits good heat transfer characteristics and found suitable for heat exchanger application.<#LINE#>Beck M.P., Sun T. and Teja A.S. (2007).@The thermal conductivity of alumina nanoparticles dispersed in ethylene glycol.@Fluid Phase Equilib, 260, 275-278.@Yes$Eastman J.A., Choi SUS, Li S, Yu W and Thomson L.J. (2001).@Anomalously increased effective thermal conductivities of ethylene glycol-based nanofluids containing copper nanoparticles.@Appl Phys Lett, 78, 718-720.@Yes$Masuda H., Ebata A., Teramae K. and Hishinuma N. (1993).@Alteration of thermal conductivity and viscosity of liquid by dispersing ultra-fine particles (dispersion of &#947;-Al2O3, SiO2, and TiO2 ultra-fine particles).@Netsu Bussei, 7, 227-233.@Yes$Li C.H. and Peterson G.P. (2006).@Experimental investigation of temperature and volume fraction variations on the effective thermal conductivity nanoparticle suspensions (nanofluids).@J Appl Phys, 99, 084314.@Yes$Timofeeva E.V., Gavrilov A.N., McCloskey J.M. and Tolmachev Y.V. (2007).@Thermal conductivity and particle agglomeration in alumina nanofluids: experiment and theory.@Phys Rev E, 76, 061203.@Yes$Xie H., Wang J., Xi T., Liu Y. and Ai F. (2002).@Thermal conductivity enhancement of suspensions containing nanosized alumna particles.@J Appl Phys, 91, 4568-4572.@Yes$Hwang D., Hong K.S. and Yang H.S. (2007).@Study of thermal conductivity nanofluids for the application of heat transfer fluids.@Thermochim Acta, 455, 66-69.@Yes$Nemade K.R. and Waghuley S.A. (2013).@Low operable temperature chemiresistive gas sensing by graphene-zinc oxide quantum dots composites.@Science of Advanced Materials, 6, 1-7.@Yes$Nemade K.R. and Waghuley S.A. (2014).@Role of defects concentration on optical and carbon dioxide gas sensing properties of Sb2O3/graphene composites.@Optical Materials, 36, 712-716.@Yes$Prasher R., Phelan P.E. and Bhattacharya P. (2006).@Effect of aggregation kinetics on the thermal conductivity of nanoscale colloidal solutions (Nanofluid).@Nano Letters, 6, 1529-1534.@Yes
<#LINE#>Impact of Alkaline Earth Metal salts on the Thermodynamics of Clouding Behavior of Tween 80<#LINE#>Patil@V.T. <#LINE#>46-48<#LINE#>10.ISCA-RJCS-2016-150.pdf<#LINE#>Department of Chemistry, JET’s Z.B. Patil College, Dhule-424002, MS, India<#LINE#>22/3/2016<#LINE#>24/7/2016<#LINE#>The cloud point (CP) determination of non ionic surfactant in presence of additives is useful in the study of interaction between surfactant and additive. Polyoxyethylene (20) sorbitan mono-oleate (Tween 80) was used as surfactant and chlorides of some alkaline earth metals like magnesium, calcium, strontium and barium were used as additives. The addition of these additives in Tween 80 solution caused decrease in cloud point of the surfactant. The influence of alkaline earth metal salts on the cloud point of Tween 80 indicates that the clouding phenomenon results in merging of   different micelle. The thermodynamic parameters of clouding process (&#916;G0 cl, &#916;H0 cl and &#916;S0 cl) were calculated using phase separation model. The overall clouding process is exothermic which shows that clouding phenomenon is guided by enthalpy and entropy. The present work is useful for the study of surfactant-additive interaction in aqueous phase.<#LINE#>Schott H. (1969).@Hydrophile-Lipophile Balance and Cloud Points of Nonionic Surfactants.@J. Pharmac. Sci., 58(12), 1443-1449.@Yes$Nakagawa T and Shinoda K (1963).@Colloidal Surfactants.@Academic Press, New York, Chapter 2, 97–178. ISBN 10: 0126400504.@Yes$Ghosh S and Moulik S.P. (1999).@The clouding behaviours of binary mixtures of polyoxyethylene(10)cetylether (Brij-56) with polyvinyl alcohol(PVA) and methyl cellulose (MC).@Indian J Chem., 38(A), 201-208.@Yes$Maclay W. N. (1956).@Factors affecting the solubility of nonionic emulsifiers.@J Colloid. Sci., 11, 272-285.@Yes$Arai H. (1967).@The relationship between the cloud points and the properties of micelles of nonionic detergents.@J Colloid. Interface Sci., 23(3), 348-351.@Yes$Schick M.J. (1962).@Surface films of nonionic detergents-I. Surface tension study.@J Colloid. Sci., 17(9), 801-813.@Yes$Doren A and Goldfarb J (1970).@Electrolyte effects on micellar solutions of nonionic detergents.@J Colloid. Interface Sci., 32(1), 67-72.@Yes$Mahajan R.K., Chawla J and Bakshi M. (2004).@Depression in cloud point of Tween in the presence of glycol additives and triblock polymers.@Colloid Polym Sci., 282, 1165-1168.@Yes$Kjellander R and Florin E. (1981).@Water structure and changes in thermal stability of the system poly (ethylene oxide)–water.@J Chem Soc. Faraday Trans.1, 77(9), 2053-2077.@Yes$Bhadane B.S. and Patil T.J. (2010).@Micellization studies on binary mixture of Methionine with Polyoxyethylene (10) Cetyl ether (Brij-56) and Polyoxyethylene (20) Cetyl ether (Brij-58).@E J Chem, 7(4), 1578-1583.@Yes$Attwood D and Florence A.T. (1983).@Surfactant Systems.@Chapman and Hall Ltd London,  99-100, ISBN: 0-412-14840-4.@Yes$Patil T.J. and Patil H.A. (2005).@Thermodynamics of solubilization of Triton-X in pure and mixed system with Polyacrylamide.@Int J Chem Sci., 3(3), 507-512.@No