Research Journal of Chemical Sciences ______ ______________________________ ______ ____ ISSN 2231 - 606X Vol. 2 ( 5 ), 1 7 - 22 , May (201 2 ) Res.J.Chem.Sci. International Science Congress Association 17 Mass Attenuation Coefficient Measurements in Soil Sample Chaudhari Laxman 1 and Raje Dayanand 2 1 Nuclear Research Laboratory, Department of Physics, Nowrosjee Wadia College, Pune - 411001, MS, INDIA 2 Department of Physics, Rajarshi Shahu Mahavidyalaya, Latur - 413512, MS, INDIA Available online at: www.isca.in (Received 23 rd February 201 2 , revised 3 rd March 201 2 , accepted 5 th March 201 2 ) Abstract Mass attenuation coefficients of soil sample in Nanded District (M.S.,India) using gamma ray energies 360 to 1330 keV have been measured. The mass attenuation coefficient usually depends upon the energy of radiations and nature of the mate rial. The result represented in the form of graph. Exponential decay was observed. This validates the gamma absorption law. Key words: Attenuation coefficient, gamma ray energy sources, gamma ray spectrometer, NaI (Tl) detector, etc . Introduction The study of interaction of gamma radiations with the materials of common and industrial use, as well as of biological and commercial importance has become major area of interest in the field of radiation science. For a scienti fic study of interaction of radiation with matter a proper characterization and assessment of penetration and diffusion of gamma rays in the external medium is necessary. The mass attenuation coefficient usually depends upon the energy of radiations and na ture of the material. For characterization the penetration and diffusion of gamma radiation in any medium the roll of attenuation coefficient is very important. An extensive data on mass attenuation coefficients of gamma rays in compound and mixtures of d osimetric interest have been studied by Hubbel 1 in the energy range of 1 kev to 20 Mev. An updated version of attenuation coefficients for elements having atomic number from 1 - 92 and for 48 additional substances have been compiled by Hubbell and Sheltzer 2 . Other scientists such as Bradley 3 , Cunningham 4 , Carlsson 5 , Jahagirdar 6 , Singh 7 , The reports on attenuation coefficients measured by researchers reported 8 - 24 for different energies for various samples in solid as well as liquid. The observations have been compared with values, which have been derived from application of the mixture rule by using the values for elements. In view of the importance of the study of gamma attenuation properties of materials and its various applications in science, technolog y, agriculture and human health, we have embarked on a study of the absorption properties of soil sample contains mixture of microelements having physical and chemical properties. The absorption coefficient of soil is dependent on its content and gamma - r ay energy. This work describes a study of content dependence on measurements of attenuation of gamma - radiation at gamma - ray energies 123, 360, 510, 662, 840, 1170, 1280 keV of soil sample from Nanded district , MS in India. The attenuation of gamma rays ex pressed as: I= I o exp ( -  x) (1) Where I o is the number of particles of radiation counted during a certain time duration without any absorber, I is the number counted during the same time with a thickness x of absorber between the source of radiation and the detector, and   is the linear absorption coefficient. This equation may be cast into the linear form, log I = log I o -  x i.e.  x= log (I o/ I) i.e.  = (1/x) log(I o/ I) (2) The mass absorption coefficient of Soil  s defined as,  s =  /ρ (3) Where,  s is the mass attenuation coefficient and  is the particle density of soil. The unit of  is cm - 1 and that of  s is cm 2 /gm Material and Methods The experimental arrangement is as shown in figure. The gamma ray sources sealed in plastic pencil having nominal activity 1mCi. A NaI (Tl) crystal was used as detector in conjunction with counter circuits. The whole system enclosed in a lead castle. Expe rimental Setup: The e xperimental s etup is as shown in figure 2 : Research Journal of Chemical Sciences ______ _ _ _______________________________ ______________ _ ____ ISSN 2231 - 606X Vol. 2 ( 5 ), 17 - 22 , May (201 2 ) Res.J.Chem.Sci International Science Congress Association 18 Figure - 1 Figure - 2 A cylindrical plastic container for soils of internal diameter 3.2 cm placed in between detector and source as in figure. The path length of soil for Gamma ray transmission (x) = 7 cm. Source, Cylinder kept in a stand. The assembly was placed over the detector. The distance between detector and source was 15.2 Cm. The transmitted and scattered Gamma rays were detected using USB - MCA along with external NaI(Tl) detector First, the cylinder was kept empty keeping acquisition time 1800 sec and readings were taken for gamma rays of a particular energy and noted as Io. Thereafter, the pat h length(x) of soil kept 7 cm and readings taken as I. Same proce dure used for each samples and v arious s ources. Results and Discussion Experimental values of number of particles of radiation without absorber (I o ) per number of particles of radiation co unted with absorber (I) were linearly increased with increasing thickness (i.e. path length in cm) as shown in following graphs. The slope of these graphs gives the value of the linear absorption coefficient. Multi - channel Analyzer Computer Gamma Source Soil Sample Pb ccas tle Stand Research Journal of Chemical Sciences ______ _ _ _______________________________ ______________ _ ____ ISSN 2231 - 606X Vol. 2 ( 5 ), 17 - 22 , May (201 2 ) Res.J.Chem.Sci International Science Congress Association 19 Table - 1 Chemical and Physical Properties Sr. No. Properties Soil Sample Contents kg/hect (Percentage) ( A) CHEMICAL PROPERTIES 1 pH 7.74 2 Salty(EC) (Mesa /Cm ) 0.30 3 Org. Compound C% 1.39 4 Sulphur (kg/hector) S 28.38 5 Phosphorous (kg/hector) P 310.46 6 Calcium Ca% 37.50 7 Magnesium Mg% 49.16 8 Sodium Na% 12.71 9 Ca Co 3 % ( Free Ca %) 5.25 B) PHYSICAL PROPERTIES 1 a) Sand% 48.31 b) Sandy/loam/clay loam% 15.10 c)Clay% 36.48 2 Moistness% 4.12 3 Water holding capacity% 51.05 4 Particle density (gm/cc) 2.43 5 Appearance of density (gm/cc) 1.41 6 Porosity 58.90 7 Increase in size% 33.43 Table - 2 Soil testing report of microelements Sr. No. Properties Normal percentage (PPM) Observed percentage for soil sample (PPM) 1 Copper (Cu) 0.2 3.72 2 Iron (Fe) 4.5 4.90 3 Manganese (Mg) 2 2.12 4 Zinc (Zn) 0.65 0.62 Figure – 3 Figure - 4 Thickness v/s Io/I for 123 keV Thickness v/s Io/I for 360 keV Research Journal of Chemical Sciences ______ _ _ _______________________________ ______________ _ ____ ISSN 2231 - 606X Vol. 2 ( 5 ), 17 - 22 , May (201 2 ) Res.J.Chem.Sci International Science Congress Association 20 Figure - 5 Figure - 6 Thickness v/s Io/I for 510 keV Thickness v/s Io/I for 662 keV Figure - 7 Figure - 8 Thickness v/s Io/I for 840 keV Thickness v/s Io/I for 1170 keV Research Journal of Chemical Sciences ______ _ _ _______________________________ ______________ _ ____ ISSN 2231 - 606X Vol. 2 ( 5 ), 17 - 22 , May (201 2 ) Res.J.Chem.Sci International Science Congress Association 21 Figure - 9 Figure - 10 Thickness v/s Io/I for 1280 keV Energy v/s mass attenuation coefficient Graph of e nergy v/s mass attenuation coefficient soil sample plotted below. Exponential decay was observed. This gives the validity of exponential absorption law, I = I 0 e - x where, x is thickness of the soil sample. This confirms the contribution of photoelectric absorption, c ompton scattering and pair production to the absorption of gamma rays by the soil sample s. Conclusion The effect of physical components like sand, moistness, water holding capacity, particle density, porosity etc. and chemical components like C, S, P, Ca, Na, Cu, Fe, Mg, Zn, CaCO 3 , etc. on linear and mass attenuation coefficient of soil sam ples have been investigated at eight gamma ray energies from 123 keV to 1280 keV. These parameters usually depend on the energy of the radiations and composite materials of the s oil and are useful for quantitative evaluation of interaction of gamma rays wi th various components in the s oil samples. As energy increases the mass attenuation coefficient of soil samples decreases. The mass attenuation coefficient values are useful for quantitative evaluation of interaction of gamma radiations with soil sample. T his method is useful for the study of properties the soils in agriculture purposes. Acknowledgement Authors are thankful to Prin. Dr. M.M. Andar, Secretary, M.E. Society, Pune, Prin. Dr. B.B. Thakur, Principal, Nowrosjee Wadia College, Pune, Dr. S.L. Bonde, Vice - Principal, Dr. K.V.Desa, Head, Dept. of Physics, Nowrosjee Wadia College for encouragement to us. Authors are also thankful to U.G.C.W.R.O., Pune and B.C.U.D., University of Pune, Pune for providing financial support for research. References 1. Hubbell J.H., Photon mass attenuation and energy absorption coefficients from 1 keV to 20 keV, Appli. Radiat. Isot., 33 , 1269 (1982) 2. Hubbel J.H. and Sheltzer S.M., Tables of X - ray mass attenuation coefficient and mass energy absorption coefficients 1 keV to 230 MeV for elements z=1 to 92 and 48 additional substances of dosimetric interest., NISTIR - 5632 (1995) 3. Bradley D.D., Chong C.S., Shukri A., Tajuddin A .A. and Ghose A.M., A new method for the direct measurement of the energy absorbtion coefficient of gamma rays, Nucl. Instrum. Meth.Phys. Res., A280 , 39 (1989) 4. Cunningham J.R. and Johns H.E., Calculation of the average energy absorbed in photon interactions , Med. Phys 7 , 51 (1980) 5. Carlsson G.A ., Absorbed Dose Equations , On the Derivation of a General Absorbed Dose Equation and Equations Valid for Different Kinds of Radiation Equilibrium , Radiation research, 5 , 219 - 237 (1981) 6. Jahagirdar H.A., Hanumaiah B. and Thontadarya B.R., Determination of narrow beam attenuation coefficients from broad beam geometrical configuration for 320KeV photons. Int., Appli. Radiat. Isot , 43, 1511 (1992) Research Journal of Chemical Sciences ______ _ _ _______________________________ ______________ _ ____ ISSN 2231 - 606X Vol. 2 ( 5 ), 17 - 22 , May (201 2 ) Res.J.Chem.Sci International Science Congress Association 22 7. Singh K., Bal H.K., Sohal I.K. and Sud S.P., Measurement of absorption coefficients at 662 keV in soil samples, Applied radiation Isotop, 42 , 1239 (1991) 8. Gerwad L., Comments on attenuation co - efficients of 123 KeV gamma radiation by dilute solutions of sodium chloride, Appl. Radiat. Isot. , 47, 19 149 (1996) 9. Gerward L., On the attenuation of X - rays and gamma rays in dilute solutions, Radiat. Phys. Chem. 48, 697 (1996) 10. Bhandal G.S., Study of Photon attenuation coefficients of some multielement materials, Nuclear Science and Engineering, 116, 218 - 222 (1994) 11. El - Kateb A.H. and Abdul Hamid., Photon attenuation study of some materials containing Hydrogen, Carbon and Oxygen ., Applied radiat.Isot., 42 , 303 - 307 (1991) 12. Singh Jarnail, Singh Karamjit, Mudahar S and Kulwant S. Gamma ray attenuati on studies in Telurite glasses, National Symposia on radiation Physics, 15, 36 - 39 (2003) 13. Demir D. Ozgul A. , Un. M. and Sachin Y . , Determination of Photon attenuation Coefficioent, Porocity and field capacity of soil by gamma ray transmission for 60,356 and 662 keV gamma rays., Applied Radiation and Isotopes, 66, 1834 - 1837 (2008) 14. Appoloni C.R. and Rios E.A, Mass attenuation coefficients of Brazilian soils in the range10 - 1450 keV, Applied Radiat.Isot, 45 , 287 - 291 (1994) 15. Teli M.T., Chaudhari L.M. and Malode S.S., Attenuation coefficients of 123 keV gamma radiation by dilute solution of sodium chloride, Appli. Radiat isot , 45(10) , 987 (1994) 16. Teli M.T., Chaudhari L.M. and Malode S.S., Study of absorption of 123 keV gamma radiation by dilute solution of zinc sulphate , J. of Pure and applied Physics, 32 , 410 (1994) 17. Teli M.T., Chaudhari L.M., Attenuation coefficient of 662 keV gamma radiation by dilute solutions of sodiu m chloride, Appli.Radiat. Isot., 461 , 369 (1995) 18. Teli M.T. and Chaudhari L.M., Linear attenuation coefficient of gamma radiation in dilute solutions of potassium chloride , Appli.Radiat. Isot., 47 , 365 (1996) 19. Teli M.T. , Answer to the comments by L. Gerward, Appli.Radiat. Isot , 48 , 87 (1997) 20. Teli M.T. , On the attenuation of X - rays and gamma rays for aqueous solutions of salts, Radiat. Phys. and Chem. , 53 (1998) 21. Teli M.T., Nathuram R. and Mahajan C.S., Radiat Meas. , 32 , 329 (2000) 22. Raje D.V. and Chaudhari L.M., Mass attenuation coefficients of soil samples in Maharashtra State (India) by using gamma energy at 0.662 MeV, Bulg. J. Phys., 37 , 158 - 164 ( 2010) 23. Chaudhari L.M. and Nathuram R., Absorption coefficient of polymers (Polyvinyl A lcohol) by using gamma energy of 0.39 MeV, Bulg. J. Phys. , 38 (2010) 24. Chaudhari Laxman M. and Raje Dayanand V., Study of photon attenuation coefficient of soil samples from Maharashtra and Karnataka states (India) from 122 keV to 1330 keV., Research Journal of Chemical Sciences , 2(2) (2012)