International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

1-N-Heterocyclic Carbene (NHC) - Catalyzed transformations for the synthesis of heterocycles requirements

Author Affiliations

  • 1Department of Chemistry, Silver Oak University, Ahmedabad, Gujarat, India
  • 2Department of Chemistry, University of Technology, Jaipur, Rajasthan, India

Res. J. Recent Sci., Volume 13, Issue (2), Pages 6-18, April,2 (2024)

Abstract

The usage of transition metals and N-heterocyclic carbenes (NHCs) has advanced recently, and this paper gives a basic summary of such developments. How well and how far these NHC ligands-containing complexes can be expanded in catalysis are the main topics of investigation. Additionally, the most recent advancements in NHC applications in organ catalysis are addressed, as is the significance of nucleophilic carbenes as organ impetuses. It is generally agreed that the addition of N-heterocyclic carbenes (NHCs) ligands has given impetus design a fresh perspective. The study of materials involves a subgroup of large-scale cyclic particles that have acted as artificial hosts and permitted subatomic recognition. In recent years, analysts have pushed for the creation of interconnected particles with well-defined patterns and properties. Researchers have therefore multiplied large-scale cyclic complex-based NHCs with numerous complexity modes that offer a wider range of visiting contexts. Recent developments in the synthesis, production, and uses of NHC in the context of full-scale cycles are highlighted in this audit. The structures displayed outstanding impetus movement, optical capacity, and coordination with various metal ions.

References

  1. Ezugwu, C. I., Kabir, N. A., Yusubov, M., & Verpoort, F. (2016)., Metal–organic frameworks containing N-heterocyclic carbenes and their precursors., Coordination Chemistry Reviews, 307, 188-210.
  2. Hameury, S., de Frémont, P., & Braunstein, P. (2017)., Metal complexes with oxygen-functionalized NHC ligands: synthesis and applications., Chemical Society Reviews, 46(3), 632-733.
  3. Hu, C., Li, X., Wang, W., Zhang, R., & Deng, L. (2014)., Metal-N-heterocyclic carbene complexes as anti-tumor agents., Current medicinal chemistry, 21(10), 1220-1230.
  4. Braga, A. L., Mota, C. J. A., & Gagosz, F. (2016)., Recent Advances in 1, 3-Diaryl-1, 3-dihydroisobenzofuran Synthesis via N-Heterocyclic Carbene Catalyzed Reactions., Synthesis, 48(17), 2703-2713.
  5. Peltier, J. L., & Nolan, S. P. (2014)., N-heterocyclic carbene catalysis: recent developments and applications in organic synthesis., Tetrahedron, 70(25), 4063-4093.
  6. Pavithra, T., Devi, E. S., & Maheswari, C. U. (2021)., Recent Advances in N‐Heterocyclic Carbene Catalyzed Oxidative Cyclization for the Formation of Heterocycles., Asian Journal of Organic Chemistry, 10(8), 1861-1883.
  7. Gagosz, F. (2011)., Recent advances in N-heterocyclic carbene catalyzed reactions., Chemical Society Reviews, 40(12), 5943-5954.
  8. Fustero, S., Sánchez-Roselló, M., & Barrio, P. (2014)., Recent advances in N-heterocyclic carbene-catalysed reactions., Chemical Society Reviews, 43(9), 3503-3523.
  9. Enders, D., Niemeier, O., & Henseler, A. (2007)., Organocatalysis by N-heterocyclic carbenes., Chemical Reviews, 107(12), 5606-5655.
  10. Lazreg, F., Nahra, F., & Cazin, C. S. (2015)., Copper–NHC complexes in catalysis., Coordination Chemistry Reviews, 293, 48-79.
  11. Li, X., Zhou, J., & Zhuo, S. (2016)., Recent progress of supported N-Heterocyclic carbene catalyst in organic reactions., Chinese Journal of Organic Chemistry, 36(7), 1484.
  12. Mahatthananchai, J., & Bode, J. W. (2014)., On the mechanism of N-heterocyclic carbene-catalyzed reactions involving acyl azoliums., Accounts of chemical research, 47(2), 696-707.
  13. Matsuoka, S. I. (2015)., N-Heterocyclic carbene-catalyzed dimerization, cyclotetramerization and polymerization of Michael acceptors., Polymer Journal, 47(11), 713-718.
  14. Menon, R. S., Biju, A. T., & Nair, V. (2016)., Recent advances in N-heterocyclic carbene (NHC)-catalysed benzoin reactions., Beilstein Journal of Organic Chemistry, 12(1), 444-461.
  15. Nasr, A., Winkler, A., & Tamm, M. (2016)., Anionic N-heterocyclic carbenes: Synthesis, coordination chemistry and applications in homogeneous catalysis., Coordination Chemistry Reviews, 316, 68-124.
  16. Peris, E. (2017)., Smart N-heterocyclic carbene ligands in catalysis., Chemical reviews, 118(19), 9988-10031.
  17. Ren, Q., Li, M., Yuan, L., & Wang, J. (2017)., Recent advances in N-heterocyclic carbene catalyzed achiral synthesis., Organic & Biomolecular Chemistry, 15(22), 4731-4749.
  18. Reyes, E., Uria, U., Carrillo, L., & Vicario, J. L. (2017)., Enantioselective cascade reactions under N-heterocyclic carbene catalysis., Synthesis, 49(03), 451-471.
  19. Wegner, S., & Janiak, C. (2017)., Metal nanoparticles in ionic liquids., Topics in Current Chemistry, 375, 1-32.
  20. Zhang, D., & Zi, G. (2015)., N-heterocyclic carbene (NHC) complexes of group 4 transition metals., Chemical Society Reviews, 44(7), 1898-1921.