International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Study of catalysts used in pyrolysis of plastic for enhancing gasoline fraction – A Review

Author Affiliations

  • 1Department of Applied Science, COEP Technological University, Pune 411005, India
  • 2Department of chemistry, MES Abasaheb Garware College Pune 411004, India

Res.J.chem.sci., Volume 14, Issue (1), Pages 53-62, February,18 (2024)

Abstract

Plastics are usually synthetic or semi-synthetic polymers with high molecular mass and can be moulded onto solid objects of different sizes and shapes. Plastics are with limitless numbers of useful characteristics, and colours, and are easy to manufacture. Plastics have major applications in the field of automotive, building constructions, medical devices, electrical and electronics, industrial machinery, Packaging etc, because of the wide spread of plastic use plastic become an integral part of our life. Once the plastic is discarded it becomes waste and it acts as a pollutant. Accumulation of plastic waste in the environment affects human as well as wildlife habitats on earth. The main disadvantage of plastic waste is that it takes around 500 years to decompose. Recycling waste plastic using the pyrolysis process can be beneficial as it converts waste into energy. Pyrolysis is the endothermic irreversible thermochemical degradation and decomposition of complex long-chain organic polymer molecules into units of simple short-chain compounds at temperatures greater than 3000C in the absence of atmospheric oxygen, with or without the application of pressure. The liquid product is oil-like material and has properties similar to diesel as plastics are originally petroleum-based products. To make pyrolysis more effective by using a catalyst which can be lower the temperature and enhance the efficiency of the reaction to produce liquid oil with characteristics of gasoline or diesel.

References

  1. Islam, M. N., & Beg, M. R. A. (2004)., Fixed bed pyrolysis of waste plastic for alternative fuel production., J. Energy Environ, 3, 69-80.
  2. Qinglan, H., Chang, W., Dingqiang, L., Yao, W., Dan, L., & Guiju, L. (2010)., Production of hydrogen-rich gas from plant biomass by catalytic pyrolysis at low temperature., International Journal of Hydrogen Energy, 35(17), 8884-8890.
  3. Vasile, C., & Brebu, M. A. (2006)., Thermal valorisation of biomass and of synthetic polymer waste. Upgrading of pyrolysis oils., Cellulose chemistry and technology, 40(7), 489.
  4. Fodor, Z., & Klemeš, J. J. (2012)., Waste as alternative fuel–Minimising emissions and effluents by advanced design., Process safety and environmental protection, 90(3), 263-284.
  5. Al-Salem, S. M., Lettieri, P., & Baeyens, J. (2009)., Recycling and recovery routes of plastic solid waste (PSW): A review., Waste management, 29(10), 2625-2643.
  6. Panda, A. K., Singh, R. K., & Mishra, D. K. (2010)., Thermolysis of waste plastics to liquid fuel: A suitable method for plastic waste management and manufacture of value added products—A world prospective., Renewable and Sustainable Energy Reviews, 14(1), 233-248.
  7. Kaminsky, W., & Kim, J. S. (1999)., Pyrolysis of mixed plastics into aromatics., Journal of Analytical and Applied Pyrolysis, 51(1-2), 127-134.
  8. Ratnasari, D. K., Nahil, M. A., & Williams, P. T. (2017)., Catalytic pyrolysis of waste plastics using staged catalysis for production of gasoline range hydrocarbon oils., Journal of analytical and applied pyrolysis, 124, 631-637.
  9. Ivanova, S. R., Gumerova, E. F., Minsker, K. S., Zaikov, G. E., & Berlin, A. A. (1990)., Selective catalytic degradation of polyolefins., Progress in polymer science, 15(2), 193-215.
  10. Zhao D.Wu M. Kou Y. and Min E. (2002)., Ionic liquids: Applications in catalysis., Catalysis Today, 74, 1-2.
  11. Aguado J. Serrano D. P. and Escola J. M. (2006)., Catalytic Upgrading of Plastic Wastes. Feedstock Recycling and Pyrolysis of Waste Plastics., Converting Waste Plastics into Diesel and Other Fuels, 73–110.
  12. Miandad, R., Barakat, M. A., Rehan, M., Aburiazaiza, A. S., Ismail, I. M. I., & Nizami, A. S. (2017)., Plastic waste to liquid oil through catalytic pyrolysis using natural and synthetic zeolite catalysts., Waste Management, 69, 66-78.
  13. Obeid, F., Zeaiter, J., Ala’a, H., & Bouhadir, K. (2014)., Thermo-catalytic pyrolysis of waste polyethylene bottles in a packed bed reactor with different bed materials and catalysts., Energy conversion and management, 85, 1-6.
  14. Weitkamp, J. (2000)., Zeolites and catalysis., Solid State Ionics 131(1–2):p. 175–188.
  15. Park, J. W., Kim, J. H., & Seo, G. (2002)., The effect of pore shape on the catalytic performance of zeolites in the liquid-phase degradation of HDPE., Polymer degradation and stability, 76(3), 495-501.
  16. Bagri R. & Williams P. T. (2002)., Catalytic pyrolysis of polyethylene., Analytical and Applied Pyrolysis, 63(1), 29–41.
  17. Li K. Lei J. Yuan G. Weerachanchai P. Wang J. Y. Zhao J. and Yang Y. (2017)., Fe-, Ti-, Zr- and Al-pillared clays for efficient catalytic pyrolysis of mixed plastics., Chemical Engineering Journal, 317, 800–809.
  18. Rehan, M., Miandad, R., Barakat, M. A., Ismail, I. M. I., Almeelbi, T., Gardy, J., ... & Nizami, A. S. (2017)., Effect of zeolite catalysts on pyrolysis liquid oil., International Biodeterioration & Biodegradation, 119, 162-175.
  19. Rusnadi, I., Aswan, A., & Daniar, R. (2021)., Catalytic Pyrolysis of High Density Polyethylene (HDPE) and Polystyrene Plastic Waste Using Zeolite Catalyst to Produce Liquid Fuel., In 4th Forum in Research, Science, and Technology (FIRST-T1-T2-2020) (62-66). Atlantis Press.
  20. López, A., De Marco, I., Caballero, B. M., Laresgoiti, M. F., Adrados, A., & Aranzabal, A. (2011)., Catalytic pyrolysis of plastic wastes with two different types of catalysts: ZSM-5 zeolite and Red Mud., Applied Catalysis B: Environmental, 104(3-4), 211-219.
  21. Schirmer, J., Kim, J. S., & Klemm, E. (2001)., Catalytic degradation of polyethylene using thermal gravimetric analysis and a cycled-spheres-reactor., Journal of analytical and applied pyrolysis, 60(2), 205-217.
  22. Onu, P., Vasile, C., Ciocılteu, S., Iojoiu, E., & Darie, H. (1999)., Thermal and catalytic decomposition of polyethylene and polypropylene., Journal of Analytical and Applied pyrolysis, 49(1-2), 145-153.
  23. Budsaereechai, S., Hunt, A. J., & Ngernyen, Y. (2019)., Catalytic pyrolysis of plastic waste for the production of liquid fuels for engines., RSC advances, 9(10), 5844-5857.
  24. Anene, A. F., Fredriksen, S. B., Sætre, K. A., & Tokheim, L. A. (2018)., Experimental study of thermal and catalytic pyrolysis of plastic waste components., Sustainability, 10(11), 3979.
  25. Aguado, J., Sotelo, J. L., Serrano, D. P., Calles, J. A., & Escola, J. M. (1997)., Catalytic conversion of polyolefins into liquid fuels over MCM-41: comparison with ZSM-5 and amorphous SiO2−Al2O3., Energy & Fuels, 11(6), 1225-1231.
  26. Sivagami, K., Divyapriya, G., Selvaraj, R., Madhiyazhagan, P., Sriram, N., & Nambi, I. (2021)., Catalytic pyrolysis of polyolefin and multilayer packaging based waste plastics: a pilot scale study., Process Safety and Environmental Protection, 149, 497-506.
  27. Singh M. V. Kumar S. and Sarker M. (2018)., Waste HD-PE plastic, deformation into liquid hydrocarbon fuel using pyrolysis-catalytic cracking with a CuCO3 catalyst., Sustainable Energy and Fuels. 2(5), 1057–1068.
  28. Kunwar, B., Moser, B. R., Chandrasekaran, S. R., Rajagopalan, N., & Sharma, B. K. (2016)., Catalytic and thermal depolymerization of low value post-consumer high density polyethylene plastic., Energy, 111, 884-892.
  29. Sakata, Y., Uddin, M. A., Muto, A., Kanada, Y., Koizumi, K., & Murata, K. (1997)., Catalytic degradation of polyethylene into fuel oil over mesoporous silica (KFS-16) catalyst., Journal of Analytical and Applied Pyrolysis, 43(1), 15-25.
  30. Sonawane, Y. B., Shindikar, M. R., & Khaladkar, M. Y. (2017)., High calorific value fuel from household plastic waste by catalytic pyrolysis., Nature Environment and Pollution Technology, 16(3), 879.
  31. Cocchi M. de Angelis D. Mazzeo L. Nardozi P. Piemonte V. Tuffi R. and Ciprioti S. V. (2020)., Catalytic pyrolysis of a residual plastic waste using zeolites produced by coal fly ash., Catalysts, 10(10), 1–17.
  32. Panda A. and Singh R. K. (2013)., Experimental optimization of process for the thermo-catalytic degradation of waste polypropylene to liquid fuel Experimental investigations of bio oil in a DI diesel engine View project pyrolysis process View project., Advances in Energy Engineering (AEE), 1(3),74-84.
  33. Hazrat M. A. Rasul M. G. and Khan M. M. K. (2015)., A study on thermo-catalytic degradation for production of clean transport fuel and reducing plastic wastes., Procedia Engineering, (105), 865–876.
  34. Shah J. Jan M. R. Mabood F. and Jabeen F. (2010)., Catalytic pyrolysis of LDPE leads to valuable resource recovery and reduction of waste problems, Energy Conversion and Management., Energy Conversion and Management, 51(12), 2791-2801.
  35. Buekens A. G. and Huang H. (1998)., Catalytic plastics cracking for recovery of gasoline-range hydrocarbons from municipal plastic wastes., Resources, Conservation and Recycling, 23, 163- 181.
  36. Uemichi Y. Kashiwaya Y. Ayame A. and Kanoh H. (1984)., Formation of aromatic hydrocarbons in degradation of polyethylene over activated carbon catalyst., Chemistry Letters, 41-44.
  37. Uemichi Y. Makino, Y. & Kanazuka T. (1989)., Degradation of polyethylene to aromatic hydrocarbons over metal-supported activated carbon catalysts., Journal of Analytical and Applied Pyrolysis, 14(4), 331-344.
  38. Serrano D. P. Aguado J. & Escola J. M. (2000)., Catalytic conversion of polystyrene over HMCM-41, HZSM-5 and amorphous SiO2-Al2O3: comparison with thermal cracking. In Applied Catalysis B: Environmental, 25, 181-189., undefined
  39. Anil H. Cakici A. I. Yanik J. U ar S. and Karayildirim T. (2004)., Utilization of red mud as catalyst in conversion of waste oil and waste plastics to fuel., Journal of Material Cycles and Waste Management, 6(1), 20–26.