International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Heena (Lawsonia inermis L.) as a green inhibitor for prevention of metals and alloys from corrosion-A Review

Author Affiliations

  • 1Department of Chemistry, Navyug Science College, Surat, India

Res.J.chem.sci., Volume 14, Issue (1), Pages 45-52, February,18 (2024)

Abstract

Henna has been used as green corrosion inhibitor for prevention of various metals and alloys such as Al, MS, CS, SS, iron, zinc, copper, tin and brass in various media like acidic, basic or neutral. A percentage of I.E. of Heena was determined by using various techniques such as WL, PDP and EIS. Film occur on metal surface has been studied by using SEM, FT-IR, UV-Vis. spectroscopy and EDX techniques. Phsysorption of Henna extract on metal surface was found to obey various isotherms. PDP study reveals that Lawsonia inermis L. can function as mixed type or anodic or cathodic type of inhibitor.

References

  1. Verma, C., Ebanso, E., Bahadur, I. & Quraishi, M.A. (2018)., An overview on plant extracts as environmental sustainable and green corrosion inhibitors for metals and alloys in aggressive corrosive media., J. Mol. Liq., 266, 577-590. https://doi.org/10.1016/j.molliq.2018.06.110.
  2. Kumar, S., Sharma, D., Yadav, P., & Yadav, M. (2013)., Experimental and quantum chemical studies on corrosion inhibition effect of synthesized organic compounds on N80 steel in hydrochloric acid., Industrial & Engineering Chemistry Research, 52(39), 14019-14029.
  3. El-Etre, A. Y. (1998)., Natural honey as corrosion inhibitor for metals and alloys. I. Copper in neutral aqueous solution., Corrosion Science, 40(11), 1845-1850.
  4. Elewady, G. Y., El-Said, I. A., & Fouda, A. S. (2008)., Effect of Anions on the Corrosion Inhibition of Aluminum in HCl using Ethyl Trimethyl Ammonium Bromide as Cationic Inhibitor., International Journal of Electrochemical Science, 3(5), 644-655.
  5. Vasudha, V. G. & Shanmuga Priya, K. (2013)., Polyalthia Longifolia as a corrosion inhibitor for mild steel in HCl solution., Research Journal of Chemical Sciences
  6. Patel, N., Rawat, A., Jauhari, S., & Mehta, G. (2010)., Inhibitive action of Bridelia retusa leaves extract on corrosion of mild steel in acidic media., European Journal of Chemistry, 1(2), 129-133.
  7. Ibrahim, T., Alayan, H., & Al Mowaqet, Y. (2012)., The effect of Thyme leaves extract on corrosion of mild steel in HCl., Progress in Organic Coatings, 75(4), 456-462.
  8. Nadkarni, K. M. (1954)., Indian materia medica, popular Book Depot., Bombay, 7, 946-948.
  9. Dev, S. (2006)., Selection of prime ayurvedic plant drugs.,
  10. Hanna, R., Maciej, J. N., Lapinsky, L., & Adamowicz, L. (1998)., Molecular structure and infra-red spectra of 2-hydroxy-1, 4-naphthaquinone; Experimental matrix isolation and theoretical Hatree-Fock and post Hatree-Fock study., Spec Act, 54, 1091-1103.
  11. Shihata, I. M., Hassan, A. B., & Mayah, G. Y. (1981)., Pharmacological effects of Lawsonia inermis leaves (el-henna).,
  12. Varier, P. S. (1997)., Indian medicinal plants: a compendium of 500 species., Vol. 5. V. Orient Longman, Hyderabad, India, 245-248.
  13. Gogaṭe, V. M. (2000)., Ayurvedic pharmacology and therapeutic uses of medicinal plants (Dravyaguna vignyan).,
  14. Khare, C. P. (2008)., Indian medicinal plants: an illustrated dictionary. Springer Science & Business Media.,
  15. Abdulmoneim, M. A. (2007)., Evalution of Lawsonia inermis Linn. Sudanese Henna) leaf Extracts as an Antimicrobial Agent., Res J of Biological Sciences, 2(4), 419-23.
  16. Alia, B. H., Bashir, A. K., & Tanira, M. O. M. (1995)., Anti-inflammatory, antipyretic, and analgesic effects of Lawsonia inermis L.(henna) in rats., Pharmacology, 51(6), 356-363.
  17. Petchiammal, A., & Selvaraj, S. (2013)., The corrosion control of aluminium using Lawsonia inermis seed extract in acid medium.,
  18. Vashi, R. T. and Prajapati, N. I. (2017)., Corrosion Inhibition of Aluminium in Hydrochloric Acid by Lawsonia inermis Leaves Extract., J. Chem. Bio. Phys. Sci., 7(4), 950-964. DOI:10.24214/jcbps.A.7.4.9564.
  19. Al-Sehaibani, H. (2000)., Evaluation of extracts of henna leaves as environmentally friendly corrosion inhibitors for metals., Mater. Wissen Werkst. Tech., 31(12), 1060-1063.
  20. Nik, W. W., Zulkifli, F., Rosliza, R., & Rahman, M. M. (2011)., Lawsonia Inermis as green inhibitor for corrosion protection of aluminium alloy., International Journal of Modern Engineering and Research Technology, 1, 723-728.
  21. Zulkifli, F., WB, W. N., Isa, M. I. N., & El-Etr, A. Y. (2018)., Corrosion inhibition of aluminium alloy 5083 by Lawsonia inermis in tropical seawater., Int. J. Mech. Eng. Technol., 9, 654.
  22. Nik, W. W., Zulkifli, F., Sulaiman, O., Samo, K. B., & Rosliza, R. (2012)., Study of Henna (Lawsonia inermis) as natural corrosion inhibitor for aluminum alloy in seawater., In IOP Conference Series: Materials Science and Engineering, 36, 1, 012043. IOP Publishing.
  23. Hajar, H. M., Zulkifli, F., Mohd Sabri, M. G., & Wan Nik, W. B. (2016)., Protection against corrosion of aluminum alloy in marine environment by Lawsonia inermis., International Journal of Corrosion, 2016.
  24. Zulkifli, F., Ali, N. A., Yusof, M. S. M., Khairul, W. M., Rahamathullah, R., Isa, M. I. N., & Wan Nik, W. B. (2017)., The effect of concentration of Lawsonia inermis as a corrosion inhibitor for aluminum alloy in seawater., Advances in Physical Chemistry, 2017.
  25. Rehan, H. H. (2003)., Corrosion control by water‐soluble extracts from leaves of economic plants., Material wissenschaft und Werkstofftechnik: Entwicklung, Fertigung, Prüfung, Eigenschaften und Anwendungen technischer Werkstoffe, 34(2), 232-237.
  26. Patel, K.K. and Vashi, R.T. (2017)., Corrosion inhibition of copper in nitric acid using Lawsonia extract as green inhibitor., J. of Corros. Sci. and Engg., 19, Paper-45.
  27. Patel, J.J. and Patel, K.N. (2017)., Leaves Extract of Lawsonia Inermis (Heena) As a Corrosion Inhibitor for Copper in Trichloro acetic Acid., J. of Appl. Chem., 6(4), 484-491.
  28. Diab, A. and Abd El-Haleema, S.M. (2022)., Corrosion Inhibition of Copper in Acidic Solution by using a Natural Product as Henna Extract (Lawsoniainermis L)., Egypt. J. Chem., 65(2), 103-111.
  29. Monika, Sharma, A. & Sharma, A. (2016)., Lawsoniainermis Leaves Extract to Impede Acid Corrosion of Copper., Int. J. of Sci. and Res., 5(12), 2138-2144, Paper ID: 11011702, DOI: 10.21275/11011702.
  30. El-Etre, A.Y., Abdallah, M. & El-Tantawy, Z. E., (2005)., Corrosion inhibition of some metals using lawsonia extract., Corros. Sci., 47(2), 385-395. DOI:10.1016/j. corsci.2004.06.006.
  31. Fouda, A.S., Hegazi, M.M. & El-Azaly, A. (2019)., Henna Extract as Green Corrosion Inhibitor for Carbon Steel in Hydrochloric Acid Solution., Int. J. Electrochem. Sci., 14, 4668-4682.
  32. Rajendran, S., Agasta, M., Devi, R. B., Devi, B. S., Rajam, K., & Jeyasundari, J. (2009)., Corrosion inhibition by an aqueous extract of Henna leaves (Lawsonia Inermis L)., Zastita Materijala, 50(2), 77-84.
  33. El-Bindary, R., El-Shamy, A. M., Elhadek, M. A. & Nassef, A. E. (2021)., Statistical Analysis of the Inhibition of Carbon Steel Corrosion in 3.5 wt. % NaCl Solution Using Lawsonia Extract., Port. Said Eng. Res. J., 25(1), 101-113. DOI: 10.21608/pserj.2020.35020.1050.
  34. Hamdy, A. and El-Gendy, N. S. (2013)., Thermodynamic, adsorption and electrochemical studies for corrosion inhibition of carbon steel by henna extract in acid medium., Egyptian J. of Petrol. 22, 17-25. https://doi.org/10.1016/j.ejpe.2012.06.002 .
  35. Singh, A. (2021)., Henna Leaves Extract as Green Corrosion Inhibitor for 304 Stainless Steel in Sulphuric Acid Solution, Int. J. for Res. in Appl. Sci. & Eng. Tech. (IJRASET), 9(VII), 2212-2214. https://doi.org/10.22214/ijraset.2021.36862., undefined
  36. Abdollahi, R. and Shadizadeh, S.R. (2012). Effect of acid additives on anticorrosive property of henna in regular mud acid, Scientia Iranica, 19(6), 1665-1671. https://doi.org/10.1016/j.scient.2012.09.006 ., undefined, undefined
  37. Abdel Rahman, H.H., Seleim, S.M., Hafez, A.M. &Helmy, A.A. (2015). Study of electropolishing inhibition of steel using natural products as a green inhibitor in ortho-phosphoric acid, Green Chem. Letters & Rev., 8(34), 88-94. https://doi.org/10.1080/17518253.2015.1111430., undefined, undefined
  38. Chetouani, A. and Hammouti, B. (2003). Corrosion inhibition of iron in hydrochloric acid solutions by naturally henna, Bull. of Electrochem., 19(1), 23–25., undefined, undefined
  39. Chaudhari, H.G. and Vashi, R.T. (2016). The study of henna leaves extract as green corrosion inhibitor for mild steel in acetic acid. J. Fundam. Appl. Sci.,8(2),280-296. http://dx.doi.org/10.4314/jfas.v8i2.8., undefined, undefined
  40. Choudhary, G. and Sharma, A.A. (2016). Impeding Acid Corrosion of Mild Steel using Green Inhibitor. Int. J. Innov. Res. Sci. Eng. Technol., 5(12), 21064. DOI:10.15680/IJIRSET.2016.0512159., undefined, undefined
  41. Ostovari, A.H., Hoseinieh, S.M., Peikari, M., Shadizadeh, S.R. & Hashemi, S.J. (2009). Corrosion inhibition of mild steel in 1 M HCl solution by henna extract: A comparative study of the inhibition by henna and its constituents (Lawsone, Gallic acid, a-D-Glucose and Tannic acid), Corros. Sci., 51(9), 1935–1949. https://doi.org/10.1016/j.corsci.2009.05.024., undefined, undefined
  42. Mahdi, S.M. (2017). Effect of Henna (Lawsonia inermis) concentration on mild steel corrosion, Int. J. of Energy and Environ., 8(4), 321-330., undefined, undefined
  43. Ramakrishnan, P. J., Janardhanan V. D. K., Sreekumar R. & Mohan, K. P. (2014). Investigation on the effect of green inhibitors for corrosion protection of mild steel in 1 M NaOH solution, Int. J. Corros., Article ID 487103, 1-5. http://dx.doi.org/10.1155/2014/487103., undefined, undefined
  44. Kumaravelan, V. and Dhivyapriya, D. (2014). Comparative study of mild steel corrosion in 1N Sulphuric acid using Aloe vera and Lawsonia inermis extract, Int. J. of Adv. Res., 2(11), 614-621., undefined, undefined
  45. Hajar, H. M., Zulkifli, F., Mohd Sabri, M.G., Fitriadhy A. & Wan Nik, W.B. (2016). Lawsonia Inermis Performance as Corrosion Inhibitor for Mild Steel in Seawater, Int. J. of Chem. Tech. Res., 9(8),600-608., undefined, undefined
  46. Karthiga, N., Prabhakar, P. & Rajendran, S. (2019). Inhibition of corrosion of mild steel in well water by an aqueous extract of lawsonia inermis leaves, Int. J. of Res. and Anal. Rev., 6(1), 437-444., undefined, undefined
  47. Devi, N.R., Karthiga, N., Keerthana, R., Uma sankareswari, T., Krishnaveni, A., Singh G. & Rajendran, S. (2020)., Extracts of leaves as corrosion inhibitors – An overview and corrosion inhibition by an aqueous extract of henna leaves (Lawsonia inermis)., Int. J. Corros. Scale Inhib., 9(4), 1169-1193. doi: 10.17675/2305-6894-2020-9-4-2.
  48. Siddekha, A. (2022)., Aqueous Plant extract of Henna leaves (Lawsonia inermis) as green corrosion inhibitors: A prescreening investigation for mild steel in a simulated environment., Int. Adv. Res. J. in Sci. Eng. and Tech., 9(2), 373-380. DOI: 10.17148/IARJSET.2022.9255.
  49. Dananjaya, S.H.S., Edussuriya, M. & Dissanayake, A.S. (2012)., Inhibition action of lawsone on the corrosion of mild steel in acidic media., TOJSAT: The Online J. of Sci. and Tech., 2(2), 32-36.
  50. Serbout, J., Touzani, R., Bouklah, M. & Hammouti, B. (2021)., An insight on the corrosion inhibition of mild steel in aggressive medium by henna extract., Int. J. Corros. Scale Inhib., 10(3), 1042–1068.
  51. Ibrahim, M. B., Sulaiman, Z., Usman, B. & Ibrahim, M.A. (2019)., Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media., World J. of Appl. Chem., 4(4), 45-51.
  52. El-Aila, H. J. Y., Aminb, N. H., Tamousec, H. M.&El- Jbooura, M. A. (2010)., Some Natural Additives as Corrosion Inhibitors for Zinc in Acetic Acid Media., Jordan J. Chem., 5(1), 61-75.
  53. Thomson, R. H. (2012)., Naturally occurring quinones IV: recent advances.,
  54. Kirkland, D., & Marzin, D. (2003)., An assessment of the genotoxicity of 2-hydroxy-1, 4-naphthoquinone, the natural dye ingredient of Henna., Mutation Research/Genetic Toxicology and Environmental Mutagenesis, 537(2), 183-199.
  55. Shastry, C. S., Kiran, U. P., & Aswathanarayana, B. J. (2012)., Effect of acute and chronic administration of the aqueous extract of Lawsonia inermis leaves on haloperidol induced catalepsy in albino mice.,
  56. Borade, A. S., Kale, B. N., & Shete, R. V. (2011)., A phytopharmacological review on Lawsonia inermis (Linn.)., Int J Pharm Life Sci, 2(1), 536-541.
  57. Mahmoud, Z. F., Abdel Salam, N.A. &Khafagy, S. M. (1980)., Constituents of henna leaves-Lawsonia inermis L growing in egypt., Fitoterapia, 51,153-5.
  58. Sharma, R. K., Goel, A. & Bhatia, A. K. (2016)., Antityphoid activity and phytochemical screening of different extracts of L. inermis plant leaves., Int. J. Curr. Res., 8, 37539-42.
  59. Siddiqui, B. S., Kardar, M. N., Ali, S. T., &Khan, S. (2003)., Two new and a known compound from Lawsonia inermis., Helvetica Chim. Acta, 86(6), 2164–2169.
  60. Rajagopalan, K.S., Subramanyan, N. & Sundaram, M. (1969)., Vapour phase corrosion inhibition of meta-dinitro benzene and beta-naphthol., Ind. J. Appl. Chem., 107, 414.
  61. Booth, G. H. and Mercer, S. J. (1964)., The effect of mimosa tannin on the corrosion of mild steel in the presence of sulphate-reducing bacteria., Corros. Sci., 4, 425-433.
  62. Musa, A. Y., Kadhum, A. A. H., Mohamad A. B. &Takriff, A. S. (2010)., Experimental and Theoretical Study on the Inhibition Performance of Triazole Compounds for Mild Steel Corrosion., Corros. Sci., 52(10), 3331-3340. https://doi.org/10.1016/j.corsci.2010.06.002.